Heteroleptic bipyridine complex: Synthesis, spectral and structural analyses, and interconversion of its {Mo3S7} core to {Mo3S4} core

Structural control in the nanoassembly of the tungsten and molybdenum dithiolene complex analog

“…26,27 Among various available ligands, dithiolene-diamides is the most attractive ligand because of its versatile use in biomedical applications and modeling of metalloenzymes. 28,29 A variety of nanoflowers that have been reported to date range from binary compounds of metal oxides such as ZnO, MnO, or metal sulfides, e.g., PbS 2 , MoS 2 , or pure metal such as cobalt or gold, and protein-encased copper phosphate nanoflowers, which are mainly grown from binary salts and involve complicated preparatory methods. 30,31 Herein, we design a simple method with a high degree of flexibility to undergo concentration driven self-assembly to nanoflowers and nanopolyhedra based on the discrete structurally characterized complexes, namely…”

“…26,27 Among various available ligands, dithiolene–diamides is the most attractive ligand because of its versatile use in biomedical applications and modeling of metalloenzymes. 28,29…”