Hexagonal Fe-based MIL-88B nanocrystals with NH2 functional groups accelerating oxytetracycline capture via hydrogen bonding

Tran, Thuan Van; Nguyen, Van Huan; Nong, Linh Xuan; Nguyen, Hong T. T.; Nguyen, Duyen Thi Cam; Nguyen, Thuong Thi; Nguyen, Hong Thi Thuy; Nguyen, Trinh Duy

doi:10.1016/j.surfin.2020.100605

Cited by 31 publications

(12 citation statements)

References 43 publications

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“…The coexistence of elements C, N, O, and Fe can be found in the XPS survey scan of NH 2 -MIL88B/TpPa-1-COF (40), suggesting the successful hybridization of NH 2 -MIL88B and TpPa-1-COF (Figure a). As can be seen in Figure b, the binding energies of 283.9, 286.1, and 288.3 eV for C 1s spectra are ascribed to the C–C, C–N–C, and C–OH (CO) bonds, respectively. , In Figure c, four peaks of the N 1s spectrum are found at 398.7, 399.5, 400.5, 402.4 eV, corresponding to the sp 2 -hybridized nitrogen in aromatic triazine rings (C–NC), primary amine species, Fe–N bond, and −N– + , respectively. ,, The O 1s spectrum (Figure d) can be resolved into three peaks with the binding energies of 530.6, 532.1, and 533.35 eV, which are ascribed to Fe–O, CO, and −OH bonds, respectively. ,,, As shown in Figure e, Fe 2p spectrum has three peaks at 711.14, 712.61, and 724.63 eV, respectively. The peaks of 711.14 and 712.61 eV correspond to Fe 2p 3/2 and that of 724.63 eV corresponds to Fe 2p 1/2 , suggesting that Fe 3+ is present in NH 2 -MIL-88B/TpPa-1-COF .…”

Section: Results and Discussionmentioning

confidence: 86%

“…26,30,31 The O 1s spectrum (Figure 4d) can be resolved into three peaks with the binding energies of 530.6, 532.1, and 533.35 eV, which are ascribed to Fe−O, C O, and −OH bonds, respectively. 6,19,31,32 As shown in Figure 4e, Fe 2p spectrum has three peaks at 711.14, 712.61, and 724.63 eV, respectively. The peaks of 711.14 and 712.61 eV correspond to Fe 2p 3/2 and that of 724.63 eV corresponds to Fe 2p 1/2 , suggesting that Fe 3+ is present in NH 2 -MIL-88B/ TpPa-1-COF.…”

Section: Resultsmentioning

confidence: 94%

“…In Figure4c, four peaks of the N 1s spectrum are found at 398.7, 399.5, 400.5, 402.4 eV, corresponding to the sp 2 -hybridized nitrogen in aromatic triazine rings (C−NC), primary amine species, Fe−N bond, and −N− + , respectively 26,30,31. The O 1s spectrum (Figure4d) can be resolved into three peaks with the binding energies of 530.6, 532.1, and 533.35 eV, which are ascribed to Fe−O, C O, and −OH bonds, respectively 6,19,31,32. As shown in Figure4e, Fe 2p spectrum has three peaks at 711.14, 712.61, and 724.63 eV, respectively.…”

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confidence: 99%

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Construction of MOF/COF Hybrids for Boosting Sunlight-Induced Fenton-like Photocatalytic Removal of Organic Pollutants

et al. 2021

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In this work, a metal−organic framework (MOF) material of NH 2 -MIL88B was hybridized with TpPa-1-COF through covalent bonding, and the hybrid was subsequently employed for the degradation of Rhodamine B (RhB) and tetracycline (TC) by simulated sunlight-induced Fenton-like exciting H 2 O 2 . The obtained results show that its photocatalytic activity is much better than those of its parent MOF and covalent organic framework (COF). Moreover, it is much higher than that of bare photocatalysis without Fenton-like excitation of H 2 O 2 . The high degradation efficiency is ascribed to two factors. One is the formation of hybrid, which promotes charge separation and light absorbance. Another is the Fenton-like excitation of H 2 O 2 , which produces more hydroxyl radicals ( • OH). This report presents a facile approach to greatly improve the photocatalytic property of MOF materials by the formation of hybrid with COFs and Fentonlike excitation of H 2 O 2 .

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Section: Results and Discussionmentioning

confidence: 86%

Section: Resultsmentioning

confidence: 94%

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confidence: 99%

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Construction of MOF/COF Hybrids for Boosting Sunlight-Induced Fenton-like Photocatalytic Removal of Organic Pollutants

et al. 2021

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“…Therefore, the treatment of antibiotic pharmaceuticals from water media by effective methods is necessarily required. Considering the non-degradable and chemically stable structure of antibiotics, adsorption may be the best remediation method due to its enormous advantages including high efficiency, fast kinetic, and tunable procedure (Tran et al 2019b , 2020d , b ; Dang et al 2021 ; Nguyen et al 2021e ). However, the selection and development of novel advanced materials for water treatment are still challenging.…”

Section: Applications Of Green Zro 2 Nanoparticlesmentioning

confidence: 99%

Green synthesis of ZrO2 nanoparticles and nanocomposites for biomedical and environmental applications: a review

et al. 2022

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Pollution and diseases such as the coronavirus pandemic (COVID-19) are major issues that may be solved partly by nanotechnology. Here we review the synthesis of ZrO 2 nanoparticles and their nanocomposites using compounds from bacteria, fungi, microalgae, and plants. For instance, bacteria, microalgae, and fungi secret bioactive metabolites such as fucoidans, digestive enzymes, and proteins, while plant tissues are rich in reducing sugars, polyphenols, flavonoids, saponins, and amino acids. These compounds allow reducing, capping, chelating, and stabilizing during the transformation of Zr 4+ into ZrO 2 nanoparticles. Green ZrO 2 nanoparticles display unique properties such as a nanoscale size of 5–50 nm, diverse morphologies, e.g. nanospheres, nanorods and nanochains, and wide bandgap energy of 3.7–5.5 eV. Their high stability and biocompatibility are suitable biomedical and environmental applications, such as pathogen and cancer inactivation, and pollutant removal. Emerging applications of green ZrO 2 -based nanocomposites include water treatment, catalytic reduction, nanoelectronic devices, and anti-biofilms.

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“…Indeed, the main advantages of adsorption such as simplicity, outstanding recyclability, and high efficiency of removal of these pharmaceuticals and others, were demonstrated [17,18]. Various materials such as metal-organic frameworks [19], ferrites [20], composite carbon nanotubes [21], activated carbons [22], and functionalized zeolites [23] have been studied as promising adsorbents. Among the materials mentioned above, ferrites such as Fe 3 O 4 , NiFe 2 O 4 , CoFe 2 O 4 , and MnFe 2 O 4 possess a special magnetic property, which enables easy separation from the solutions.…”

Section: Introductionmentioning

confidence: 99%

Facile Fabrication of Novel NiFe2O4@Carbon Composites for Enhanced Adsorption of Emergent Antibiotics

2021

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Water purification is becoming one of the most pertinent environmental issues throughout the world. Among common types of water pollution involving heavy metals, pharmaceutical drugs, textile dyes, personal care products, and other persistent organic pollutants, the pollution of antibiotic drugs is increasingly emerging due to their adverse effects on microorganisms, aquatic animals, and human health. Therefore, the treatment of such contaminants is very necessary to reduce the concentration of antibiotic pollutants to permissible levels prior to discharge. Herein, we report the use of NiFe2O4@C composites from a bimetallic-based metal-organic framework Ni-MIL-88B(Fe) for removal of ciprofloxacin (CFX) and tetracycline (TCC). The effect of production temperatures (600–900 °C), solution pH (2–10), NiFe2O4@C dose (0.05–0.2 g/L), concentration of antibiotics (10–60 mg/L), and uptake time (0–480 min) was investigated systematically. Response surface methodology and central composite design were applied for quadratic models to discover optimum conditions of antibiotic adsorption. With high coefficients of determination (R2 = 0.9640–0.9713), the proposed models were significant statistically. Under proposed optimum conditions, the adsorption capacity for CFX and TCC were found at 256.244, and 105.38 mg/g, respectively. Recyclability study was employed and found that NiFe2O4@C-900 could be reused for up to three cycles, offering the potential of this composite as a good adsorbent for removal of emergent antibiotics.

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Hexagonal Fe-based MIL-88B nanocrystals with NH2 functional groups accelerating oxytetracycline capture via hydrogen bonding

Cited by 31 publications

References 43 publications

Construction of MOF/COF Hybrids for Boosting Sunlight-Induced Fenton-like Photocatalytic Removal of Organic Pollutants

Construction of MOF/COF Hybrids for Boosting Sunlight-Induced Fenton-like Photocatalytic Removal of Organic Pollutants

Green synthesis of ZrO2 nanoparticles and nanocomposites for biomedical and environmental applications: a review

Facile Fabrication of Novel NiFe2O4@Carbon Composites for Enhanced Adsorption of Emergent Antibiotics

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