Hierarchical pore-trapped and hydrogen-bonded phosphoric acid in Pd-supported zeolite for the efficient aqueous hydrodeoxygenation of lignin derivatives at ambient temperature

Construction of Pd–TiOx interfaces for selective hydrodeoxygenation of CO bonds in vanillin by supporting Pd nanoparticles on ETS-10 zeolite

“…[7][8][9][10] For example, the catalytic hydrodeoxygenation of the C]O bond in vanillin has been widely investigated. [11][12][13][14] Currently, it has been reported that TiO 2 supported metal catalysts are efficient for the hydrodeoxygenation of biomass-based molecules. 16,17 For example, a TiO 2 supported ruthenium catalyst (Ru/TiO 2 ) exhibited >95% toluene yield in the catalytic hydrodeoxygenation of p-cresol at 160 °C; 15 porous TiO 2 encapsulating Pd nanoparticles showed high hydrodeoxygenation selectivity for aromatic alcohols/aldehydes and phenolics while maintaining high catalytic activity; 16 a highly dispersed Pt/TiO 2 catalyst with a low metal loading was reported to be efficient in the upgrading of cotton straw derived bio-oil.…”