2023
DOI: 10.1021/acs.inorgchem.3c01255
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High-Activity and High-Selectivity Air-Stable Nickel and Copper Complexes for Copolymerization of Epoxides with Anhydrides

Mei-Ling Lin,
Chen-Yen Tsai

Abstract: Ring-opening copolymerization (ROCOP) of epoxides with anhydrides presents a highly promising pathway for the synthesis of diverse polyester copolymers. This process involves the simultaneous opening of the epoxide ring and the anhydride ring, resulting in the formation of copolymer chains with alternating repeating units. Here, we synthesized a series of nickel and copper complexes coordinated by amine-bis(benzotriazole phenolate) ligands ( C1NN BiBTP-H2). Different acid–base conditions can result in the synt… Show more

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