We experimentally demonstrate a 4-Gb/s radio-over-fiber (RoF) system with 40-km fiber and 2-m wireless distance downstream at 100-GHz carrier. To the best of our knowledge, this is for the first time in China to realize optical wireless link at 100 GHz. In this letter, simple intensity modulator with direct detector (IM-DD) modulation is employed and optical power penalty after 40-km single mode fiber (SMF)-28 and 2-m air link is 3.2 dB with bit-error-rate (BER) at 1×10 −9 . OCIS codes: 060.0060, 060.2360, 060.5625. doi: 10.3788/COL201311.020608.Radio-over-fiber (RoF) technology, regarded as one of the most promising solutions to break the last mile bottleneck imposed by the copper network, has attracted much attention recently [1−11] . It features low transmission loss, extremely wide bandwidth, availability of optical amplifiers, and broad coverage by making full use of the enormous bandwidth of the fiber and the flexibility presented by wireless communication system. To realize the seamless integration of wireless and fiberoptic networks, the wireless links need to be developed to match the capacity of high-speed fiber-optic communication systems. Moreover, the access network is expected to carry more data to provide the increasing broad-band radio services such as voice over IP and video on demand. As the capacity of the air link is relate to the frequency of the carrier, a higher carrier frequency with a large bandwidth is becoming indispensable. This is due to its broad spectrum that the higher frequency W-band (75 GHz -0.11 THz), avails of us a new approach for