Vehicle Re-Identification (ReID) aims to retrieve images of vehicles with the same identity from different scenarios. It is a challenging task due to the large intra-identity discrepancy caused by viewpoint variations and the subtle inter-identity difference produced by similar appearances. In this paper, we propose a Viewpoint-Aware Loss (VAL) function to deal with these challenges. Specifically, we propose partition and reunion operations in VAL, which significantly shrinks the intra-identity distance and acquires viewpoint-invariant representations. In addition, we embed a multi-decision boundary mechanism in VAL. It contributes to enlarging the interidentity distance. A comprehensive evaluation on two benchmarks shows the superiority of our method in contrast to a series of existing state-of-the-arts.