Radiative
thermal management (RTM) is a sustainable and environmentally
friendly strategy because it needs no external energy input and can
reduce greenhouse gas emissions and thus recently has gained significant
attention. However, the material color in existing radiative cooling/heating
applications is traditionally white/black in order to maximize cooling/heating
performance, which limits their practical application range. Herein,
we propose a symmetric and asymmetric Fabry–Pérot cavity
structure to fabricate a polymer-based photonic dual-mode thermal
management film with a high-purity structural color display. The film
can be adjusted as needed to produce a colored appearance with different
hues while simultaneously maintaining sufficient radiative cooling
power. The cooling side of the color dual-mode photon film exhibits
high solar reflectivity (92.1%) and infrared emissivity (96.0%). Therefore,
the maximum radiative cooling effect in the daytime subenvironment
reaches 5.8 °C, and the maximum theoretical cooling power is
high up to 62.6 W/m2. Meanwhile, the heating side of the
dual-mode film features a very low infrared emissivity (8.2%) and
a high solar absorption rate (61.5%), and its radiative heating capacity
reaches 61.1 °C. Compared with traditional coatings, the colored
dual-mode film can save up to 10.3% of annual energy in the northern
and southern temperate zones. The color dual-mode photon film can
easily switch between cooling and heating modes by flipping to adapt
to dynamic cooling and heating scenarios, which is of great significance
for alleviating the greenhouse effect and promoting sustainable development.