Silicon nanoclusters (Si-ncs) are of substantial interest as they play a significant role in the development of Si-based light sources [1,2]. One of the main application areas is in integrated photonics for telecommunications and computing; however, there is also a substantial market for the use of these materials in lighting and displays. Lighting accounts for approximately 20% of the $60 billion electricity market in the United States [3]. The potential to tap this market, combined with the inefficiency of incandescent bulbs, has driven research over the past decades in the area of solidstate lighting (SSL). The market for both incandescent and fluorescent light sources has been steadily dwindling with a shift toward the development of more efficient, cheaper, and environment friendly alternatives, such as SSL [4,5]. In 2007, the market for LED lighting was estimated at $330 million (a 60% increase over the previous year) and is projected to grow to $1.4 billion by 2012 [6].As with light sources for integrated photonics, the SSL market relies primarily on III-V, II-VI, or phosphor-based materials and, more recently, organic light emitting diodes (OLEDs) [5]. With the ability to attain efficient luminescence in Si-nc-based systems, however, the possibility of an all-Si approach has become attractive. Such an approach would allow manufacturers to use of the same large-scale production and processing facilities as used by the microelectronics and solar cell industries while maintaining low cost. There are two performance metrics generally of interest for solid-state lighting, the performance (in lumens) per dollar and the performance per watt (efficacy). Figure 17.1 illustrates these metrics for several common lighting sources. While LED and OLED technologies currently lead in terms of efficacy, recently explored RE-doped silicon-based materials (shown on the graph as Rare Earth Films) have a clear advantage in terms of the performance per dollar (data courtesy of Group IV Semiconductor Inc.). Furthermore, integration with the necessary electronics for driving Si-based lighting cells or pixels would then be easily achieved due to the use of a Si-platform. In particular, the use of rare earth dopants to attain specific colored emissions for mixing to obtain white light presents a viable pathway to Si-based lighting. Such an approach borrows from that commonly used with color-converting phosphors, where rare earths are routinely used, while incorporating the rare earth elements into a silicon-based host for the advantages in fabrication.