2012
DOI: 10.1016/j.jallcom.2012.06.008
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High energy ball-milling preparation of Co–B amorphous alloy with high electrochemical hydrogen storage ability

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Cited by 28 publications
(13 citation statements)
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“…Based on the data, the discharge capacity enhanced from 360 mAh/g in the first cycle to 2050 mAh/g after 15 cycles. In Table 1 discharge capacity for some materials with different structures is presented 27‐31 . As can be observed, the present work shows the SnFe 12 O 19 /MWCNTs nanocomposite creates an efficient role for hydrogen storage.…”
Section: Resultssupporting
confidence: 61%
“…Based on the data, the discharge capacity enhanced from 360 mAh/g in the first cycle to 2050 mAh/g after 15 cycles. In Table 1 discharge capacity for some materials with different structures is presented 27‐31 . As can be observed, the present work shows the SnFe 12 O 19 /MWCNTs nanocomposite creates an efficient role for hydrogen storage.…”
Section: Resultssupporting
confidence: 61%
“…1. Co-P obtained from chemical reduction keeps a typical amorphous feature, as indicated by a broad peak located at a 2h value of around 45° [30,31]. For Co 2 P synthesized via the reduction of phosphate with KBH 4 , the sharp diffraction peaks with high intensity and resolution indicate a high degree of crystallization.…”
Section: Materials Characterizationmentioning
confidence: 98%
“…In the cyclic voltammogram shown in Figure (b), cathodic peaks at –1.10 and –1.00 V are due to the P–H bonding and Co ··· H interaction, respectively. Accordingly, anodic peaks at –0.92 and –0.70 V belong to the breaking of P–H bonds and the desorption of the hydrogen from the Co surface, respectively , . These redox peaks also provide evidence for the intracell Kubas‐enhanced hydrogen adsorption process in Co 2 P. In addition, it is found that the hydrogen‐storage capacity decreases at high rates of hydrogen charging/discharging, because the fast injection/extraction of hydrogen is disadvantageous to its spilling‐over process, as shown in Figure (c) and Table S3.…”
Section: Resultsmentioning
confidence: 91%