High‐Energy‐Density Materials: Synthesis and Characterization of N₅⁺[P(N₃)₆]⁻, N₅⁺ [B(N₃)₄]⁻, N₅⁺ [HF₂]⁻⋅n HF, N₅⁺ [BF₄]⁻, N₅⁺ [PF₆]⁻, and N₅⁺ [SO₃F]⁻

Preparation and Characterization of the Binary Group 13 Azides M(N3)3 and M(N3)3⋅CH3CN (M=Ga, In, Tl), [Ga(N3)5]2−, and [M(N3)6]3− (M=In, Tl)

“…As found for other binary polyazides, [8][9][10][11][12][13][14][15][19][20][21] the neutral polyazides can be stabilized either by the formation of donoracceptor adducts with Lewis bases or by anion formation, which increases the ionicity of the azido groups. Because an ionic azide group possesses two double bonds while a covalent azido group has a single and a triple bond, increasing the ionicity of the existing azido ligands by further azide addition makes the breaking of an N À N bond more difficult and enhances the activation energy barrier toward catastrophic N 2 elimination.…”

“…There has been much interest in polyazido compounds during the last two decades. [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18] In particular, the potential of Group 13 azides as precursors for the synthesis of the corresponding nitrides has been studied in great detail owing to their usefulness for semiconductor and optoelectronic applications. Although most of these efforts were devoted to gallium azides, [19,20] aluminum and indium azides were also explored.…”

Experimental Detection of Trinitramide, N(NO2)3

“…[1][2][3] Recent examples for advances in polynitrogen chemistry are the bulk synthesis of the V-shaped N 5 + , [4,5] the tetrazole-based CN 7 , À[6] and the detection of cyclic N 5 À . [7,8] Compounds containing exclusively oxygen and nitrogen are desirable for applications such as environmentally benign rocket propulsion.…”

In-situ nano-crystal-to-crystal transformation synthesis of energetic materials based on three 5,5′-azotetrazolate Cr(III) salts

“…However, the previous synthetic approaches for nano energetic materials exhibited limited control over the shape and size distribution of these particles because they are dangerous explosives111213. It is currently a prerequisite urgency and an extremely challenging task to develop the mild and universal construction methods for the further investigation of nano energetic materials1415161718. Currently, the controllable preparation of nano energetic materials with distinct structures and feature sizes is of great importance to achieve desirable properties, such as structure- and size-dependent properties, including energy density, thermal decomposition, sensitivity and operational performance1819202122.…”