A unique set of experimental measurements have been made in the LENS-XX expansion tunnel facility of the flow over a 17.8-cm spherical capsule heat shield with high enthalpy carbon dioxide test gas traveling from 3.9 to 6.4 km/s (7.6 to 23.5 MJ/kg total enthalpy). Shock shape, surface pressure, and surface heat transfer were measured during six runs and compared to computational fluid dynamics simulations. Unlike previous measurements in the LENS-I reflected shock tunnel facility, the shock shape for all run conditions was found to agree well with the prediction of shock shape and the laminar surface heat transfer distributions were found to lie midway between the predicted non-catalytic and supercatalytic heating bounds predicted, suggesting diffusion-limited finite rate catalytic behavior. The experimental dataset obtained in this study will become a pivotal set of data for validation of thermal and chemical models of Martian entry under realistic conditions.