High-lying Rydberg states of vinyl bromide studied by two-photon resonant ionization spectroscopy

Chuang, Chi-Hung; Chen, Chun-Cing; Wu, Hsing-Chen; Chen, Yit‐Tsong

doi:10.1016/j.cplett.2004.06.128

Cited by 4 publications

(1 citation statement)

References 29 publications

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“…Seven Rydberg series, including 1s, 3p, 2d, and 1f, have been identified from the excitation of vinyl bromide. 51 Further examples can be expected, but f-Rydberg series are well established for polyatomic molecules. The VUV spectrum of cyclohexane (C 6 H 12 ) 52 shows a prominent Rydberg series with members n = 4-9 converging on an IE 1 at 9.88 eV but has a missing n = 3 member.…”

Section: Discussionmentioning

confidence: 99%

The electronic states of 1,2,3-triazole studied by vacuum ultraviolet photoabsorption and ultraviolet photoelectron spectroscopy, and a comparison with ab initio configuration interaction methods

Palmer¹,

Hoffmann

Jones

et al. 2011

The Journal of Chemical Physics

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The electronic states of 1,2,3-triazole studied by vacuum ultraviolet photoabsorption and ultraviolet photoelectron spectroscopy, and a comparison with ab initio configuration interaction methods Citation for published version:Palmer, MH, Hoffmann, SV, Jones, NC, Head, AR & Lichtenberger, DL 2011, 'The electronic states of 1,2,3-triazole studied by vacuum ultraviolet photoabsorption and ultraviolet photoelectron spectroscopy, and a comparison with ab initio configuration interaction methods' The Journal of Chemical Physics, vol. 134 General rightsCopyright for the publications made accessible via the Edinburgh Research Explorer is retained by the author(s) and / or other copyright owners and it is a condition of accessing these publications that users recognise and abide by the legal requirements associated with these rights. Take down policyThe University of Edinburgh has made every reasonable effort to ensure that Edinburgh Research Explorer content complies with UK legislation. If you believe that the public display of this file breaches copyright please contact openaccess@ed.ac.uk providing details, and we will remove access to the work immediately and investigate your claim.

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Section: Discussionmentioning

confidence: 99%

The electronic states of 1,2,3-triazole studied by vacuum ultraviolet photoabsorption and ultraviolet photoelectron spectroscopy, and a comparison with ab initio configuration interaction methods

Palmer¹,

Hoffmann

Jones

et al. 2011

The Journal of Chemical Physics

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Ab initio calculations of excited states of vinyl bromide

Chang

Tsao

2006

Chemical Physics Letters

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Rydberg spectra of trans-1,2-dibromoethylene

Shi

Lipson

2007

The Journal of Chemical Physics

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(2+1) resonance-enhanced multiphoton ionization spectra of jet-cooled trans-1,2-dibromoethylene are reported for the first time. The two-photon spectral region between 149.7 and 141.2 nm was examined. A 4p(z)<--pi Rydberg transition between 66,800 and 68,000 cm(-1) with A(g) excited state symmetry was analyzed, as well as two 4f<--pi Rydberg transitions with B(g) excited state symmetry and one 4f<--pi Rydberg transition with A(g) excited state symmetry between 68,000 and 70,800 cm(-1). All Rydberg transitions observed in this work belong to series that converge to the first ionization potential of the molecule. The short vibrational progressions observed involve two totally symmetric in-plane normal modes: C=C-H bending (nu(3)) and C=C-Br bending (nu(5)) with average excited state frequencies of 829 and 226 cm(-1), respectively.

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High-lying Rydberg states of vinyl bromide studied by two-photon resonant ionization spectroscopy

Cited by 4 publications

References 29 publications

The electronic states of 1,2,3-triazole studied by vacuum ultraviolet photoabsorption and ultraviolet photoelectron spectroscopy, and a comparison with ab initio configuration interaction methods

The electronic states of 1,2,3-triazole studied by vacuum ultraviolet photoabsorption and ultraviolet photoelectron spectroscopy, and a comparison with ab initio configuration interaction methods

Ab initio calculations of excited states of vinyl bromide

Rydberg spectra of trans-1,2-dibromoethylene

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