2021
DOI: 10.1002/adsu.202100052
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High‐Performance BioNylons from Itaconic and Amino Acids with Pepsin Degradability

Abstract: dianhydro-d-mannitol (isomannide), and 1,4,3,6-dianhydro-l-iditol (isoidide). [5][6][7][8] However, low T g values of biobased polyamides restrict their application. [3][4][5][6][7][8] On the other hand, considerable progress has been made in the syntheses of enantiomeric d-and l-poly(hexamethylene di-Omethyltartaramide)s {P6DMT(d-/l-)} a pair of stereoregular polyamides is reported. [9][10][11] The (+)-3-carene based chiral polyamides such as poly-3R-caranamide and poly-3S-caranamide have high T g (70-100 °C… Show more

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Cited by 8 publications
(1 citation statement)
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“…81 Recently, the same group reported novel diacids ( M62 and M63 ) with one pyrrolidone ring using dimethyl itaconate and l -leucine methyl ester. 82 Chirally interactive high molecular weight polyamides ( M n = 62 kDa) were prepared from polycondensation with hexamethylenediamine and showed susceptibility to pepsin-degradation. To deactivate the double bond from cross-linking while introducing anti-flammability to polyamides, a phosphonated telechelic diacid ( M64 ) was made from the addition reaction of itaconic acid and DOPO.…”
Section: Di-functional Monomers For Step-growth Polymerizationmentioning
confidence: 99%
“…81 Recently, the same group reported novel diacids ( M62 and M63 ) with one pyrrolidone ring using dimethyl itaconate and l -leucine methyl ester. 82 Chirally interactive high molecular weight polyamides ( M n = 62 kDa) were prepared from polycondensation with hexamethylenediamine and showed susceptibility to pepsin-degradation. To deactivate the double bond from cross-linking while introducing anti-flammability to polyamides, a phosphonated telechelic diacid ( M64 ) was made from the addition reaction of itaconic acid and DOPO.…”
Section: Di-functional Monomers For Step-growth Polymerizationmentioning
confidence: 99%