Cooling processes
require heat transfer fluids with high specific
heat capacity. For cooling processes below 0 °C, water has to
be diluted with organic liquids to prevent freezing, with the undesired
effect of reduced specific heat capacity. Phase change dispersions,
PCDs, consist of a phase change material, PCM, being dispersed in
a continuous phase. This allows for using the PCD as heat transfer
fluid with a very high apparent specific heat capacity within a specified,
limited temperature range. So far, the PCMs being reported in the
literature are paraffins, fatty acids, or esters and are used for
isothermal cooling applications between +4 and +50 °C. They are
manufactured by high shear equipment like rotor-stator systems. A
recently published method to produce emulsions by the direct condensation
of the dispersed phase into the emulsifier-containing continuous phase
is applied on this PCD.
n
-Decane is used as PCM,
and the melting temperature is −30 °C. The achieved apparent
specific heat capacity lies above 15 kJ/kg·K, more than 3 times
the value of water. This paper presents experimental methods and data,
formulation details, and thermophysical and rheological properties
of such new PCD. Food conservation or isothermal cooling of lithium-ion
batteries is a potential application for the presented method. The
properties of the developed PCD were determined, and the successful
application of such a PCD at −30 °C has been demonstrated.