2019
DOI: 10.1021/acsami.9b16667
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High-Performance Free-Standing Flexible Photodetectors Based on Sulfur-Hyperdoped Ultrathin Silicon

Abstract: Flexible photodetectors (PDs) prepared with silicon-based materials have received considerable attention for their use in a wide range of portable and wearable applications. In this study, we present the first free-standing flexible PD based on sulfur-hyperdoped ultrathin silicon, which was fabricated using a femtosecond laser in a SF6 atmosphere. It is found that the fabricated device exhibits excellent performance of broadband photoresponse from 400 to 1200 nm, with a peak responsivity of 63.79 A/W @ 870 nm … Show more

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Cited by 37 publications
(18 citation statements)
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“…However, for a specially designed material, difficulties remain regarding fully explaining the physical mechanism of particular properties such as the asymmetric photoresponse between the forward and reverse bias, the extended infrared response, and extremely high EQE. It could depend on the impurity energy levels introduced by the sulfur atoms or the assistance of trap states, attributed to the ultrafast and extremely strong interaction between femtosecond laser and materials, which results in nonthermal melting and the fast resolidification of materials. These effects lead to complexity in the process of photoconductive gain such as the high‐density interaction of electrons and holes, the interaction of electrons and phonons, and exciton‐polariton.…”
Section: Resultsmentioning
confidence: 99%
“…However, for a specially designed material, difficulties remain regarding fully explaining the physical mechanism of particular properties such as the asymmetric photoresponse between the forward and reverse bias, the extended infrared response, and extremely high EQE. It could depend on the impurity energy levels introduced by the sulfur atoms or the assistance of trap states, attributed to the ultrafast and extremely strong interaction between femtosecond laser and materials, which results in nonthermal melting and the fast resolidification of materials. These effects lead to complexity in the process of photoconductive gain such as the high‐density interaction of electrons and holes, the interaction of electrons and phonons, and exciton‐polariton.…”
Section: Resultsmentioning
confidence: 99%
“…Fabrication techniques based on femtosecond lasers have been studied by researchers to address the various challenges encountered in the manufacturing of high-performance, versatile, and durable devices, as shown in Table IV. Flexible photodetectors consisting of micro/nanostructures were fabricated by femtosecond laser irradiation on silicon-based materials in an SF6 atmosphere [62]. The devices exhibited high responsiveness over a wide range of wavelengths owing to their high light absorption efficiency, which was attributable to the etched micro/nanostructures, as shown in Figure 5(b,i).…”
Section: F Manufacturing and Applications Of Flexible Electronic Devicesmentioning
confidence: 99%
“…Especially, the transition metal dichalcogenide (TMDCs) based on organic substrate, such as MoS 2 on PET, WSe 2 or MoS 2 /WSe 2 on paper, provide advanced flexible visible detectors with high responsivity and quantum efficiency, the preparation scheme has low cost and large device preparation area. Moreover, broadband photodetection has been achieved in TMDCs 18 , 36 , IGZO 37 and Si-based material 38 , which enhances the absorption of light by the decoration on surface with dissimilar superstructure or nanostructure. However, the flexible photodetection realized with above material is able to covers UV, Vis and NIR, but has no response to short-wave infrared (SWIR).…”
Section: Introductionmentioning
confidence: 99%