High-performance, long lifetime chloride ion battery using a NiFe–Cl layered double hydroxide cathode

Yin, Qing; Luo, Jianeng; Zhang, Jian; Zheng, Lirong; Cui, Guoqing; Han, Jingbin; O’Hare, Dermot

doi:10.1039/d0ta04290k

Cited by 63 publications

(33 citation statements)

References 42 publications

(48 reference statements)

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“…[79] Yin et al prepared NiFe-based lay-ered double hydroxide (LDH) intercalated by chloride ions as cathode materials for CIBs. [80] LDHs are a type of 2D brucitelike anionic clays. LDHs with 2D diffusion pathways had high anion-exchange capacity with reversible anion intercalation/deintercalation.…”

Section: Cathodesmentioning

confidence: 99%

Natural Clay‐Based Materials for Energy Storage and Conversion Applications

Liu

et al. 2021

Advanced Science

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Among various energy storage and conversion materials, functionalized natural clays display significant potentials as electrodes, electrolytes, separators, and nanofillers in energy storage and conversion devices. Natural clays have porous structures, tunable specific surface areas, remarkable thermal and mechanical stabilities, abundant reserves, and cost‐effectiveness. In addition, natural clays deliver the advantages of high ionic conductivity and hydrophilicity, which are beneficial properties for solid‐state electrolytes. This review article provides an overview toward the recent advancements in natural clay‐based energy materials. First, it comprehensively summarizes the structure, classification, and chemical modification methods of natural clays to make them suitable in energy storage and conversion devices. Then, the particular attention is focused on the application of clays in the fields of lithium‐ion batteries, lithium–sulfur batteries, zinc‐ion batteries, chloride‐ion batteries, supercapacitors, solar cells, and fuel cells. Finally, the possible future research directions are provided for natural clays as energy materials. This review aims at facilitating the rapid developments of natural clay‐based energy materials through a fruitful discussion from inorganic and materials chemistry aspects, and also promotes the broad sphere of clay‐based materials for other utilization, such as effluent treatment, heavy metal removal, and environmental remediation.

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Section: Cathodesmentioning

confidence: 99%

Natural Clay‐Based Materials for Energy Storage and Conversion Applications

Liu

et al. 2021

Advanced Science

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“…Along the same line, Han's group has also demonstrated high-performance CIBs using NiMn-Cl and NiFe-Cl LDHs as cathode active materials. 71,72 These recent works on LDH materials highlight the opportunity that the exploration of new chloride-hosting electrodes can help solve the most challenging and persistent problems associated with rechargeable CIBs. In particular, the negligible volume change associated with Cl − (de)intercalation into LDH materials demonstrates how new Cl − intercalation materials could mitigate the longstanding stability issues.…”

Section: Cib Electrode Materialsmentioning

confidence: 99%

A review of halide charge carriers for rocking‐chair and dual‐ion batteries

Sandstrom

Chen

2021

Carbon Energy

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This review discusses how halide ion species have been used as charge carriers in both anion rocking-chair and dual-ion battery (DIB) systems.The anion rocking-chair batteries based on fluoride and chloride have emerged over the past decade and are garnering increased research interest due to their large theoretical energy density values and the natural abundance of halide-containing materials. Moreover, DIBs that use halide species as their anionic charge carrier are seen as one of the promising next-generation battery technologies due to their low cost and high working potentials. Although numerous polyatomic anions have been studied as charge carriers, the use of single halide ions (i.e., F − and Cl − ) and metal-based superhalides (e.g., [MgCl 3 ] − ) as anionic charge carriers in DIBs has been considerably less explored. Herein, we provide an overview of some of the key advances and recent progress that has been made with regard to halide ion charge carriers in electrochemical energy storage. We offer our perspectives on the current state of the field and provide a roadmap in hopes that it helps researchers toward making new advances in these promising and emerging areas.

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“…Layered double hydroxides (LDHs) with a general formula of M 1‑ x 2+ M x 3+ (OH) 2 (A n ‑ ) x / n · y H 2 O (0.2 ≤ x ≤ 0.33) are a family of two-dimensional (2D) materials. − The exchangeable interlayer anions (A n – ) are accommodated to compensate for the positive charge generated by a fraction of edge-shared octahedral coordinated divalent metal cations replaced by trivalent ones. Due to the unique topochemical transformation feature, LDHs maintain their layered structure during redox reactions of metal elements in their host layers. − Another characteristic of LDH is that the interlaminar anions can be inserted and de-inserted reversibly with an extremely low diffusion barrier. − Therefore, owing to these features, the LDHs can be considered as potential electrodes for rechargeable fluoride-ion batteries.…”

Section: Introductionmentioning

confidence: 99%

A Zero-Strain Insertion Cathode Material for Room-Temperature Fluoride-Ion Batteries

Zhang

Wang

Zhang

et al. 2022

ACS Appl. Mater. Interfaces

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A fluoride-ion battery (FIB) is a novel type of energy storage system that has a higher volumetric energy density and low cost. However, the high working temperature (>150 °C) and unsatisfactory cycling performance of cathode materials are not favorable for their practical application. Herein, fluoride ion-intercalated CoFe layered double hydroxide (LDH) (CoFe-F LDH) was prepared by a facile co-precipitation approach combined with ion-exchange. The CoFe-F LDH shows a reversible capacity of ∼50 mAh g–1 after 100 cycles at room temperature. Although there is still a big gap between FIBs and lithium-ion batteries, the CoFe-F LDH is superior to most cathode materials for FIBs. Another important advantage of CoFe-F LDH FIBs is that they can work at room temperature, which has been rarely achieved in previous reports. The superior performance stems from the unique topochemical transformation property and small volume change (∼0.82%) of LDH in electrochemical cycles. Such a tiny volume change makes LDH a zero-strain cathode material for FIBs. The 2D diffusion pathways and weak interaction between fluoride ions and host layers facilitate the de/intercalation of fluoride ions, accompanied by the chemical state changes of Co2+/Co3+ and Fe2+/Fe3+ couples. First-principles calculations also reveal a low F– diffusion barrier during the cyclic process. These findings expand the application field of LDH materials and propose a novel avenue for the designs of cathode materials toward room-temperature FIBs.

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High-performance, long lifetime chloride ion battery using a NiFe–Cl layered double hydroxide cathode

Abstract: NiFe–Cl layered double hydroxide (LDH) is proposed as a high-capacity and long lifetime cathode material for chloride ion batteries (CIBs), which delivers a maximum capacity of 350.6 mA h g−1 and a long lifetime of 800 cycles.

Cited by 63 publications

References 42 publications

Natural Clay‐Based Materials for Energy Storage and Conversion Applications

Natural Clay‐Based Materials for Energy Storage and Conversion Applications

A review of halide charge carriers for rocking‐chair and dual‐ion batteries

A Zero-Strain Insertion Cathode Material for Room-Temperature Fluoride-Ion Batteries

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