“…Silicon nitride (Si 3 N 4 ) thin films are important for applications in microelectronics such as dielectric layers in complementary metal oxide semiconductor devices, − gate spacers, ,− and diffusion barriers. − In particular, deposition of conformal thin films at low temperatures (<300 °C) is necessary for nanopatterned, three-dimensional substrates developed to satisfy scaling requirements. , Atomic layer deposition (ALD) has emerged as one of the best methods to achieve Si 3 N 4 deposition with adequate thickness control, conformality for highly patterned substrates, and chemical specificity. − A number of precursors have been developed for the growth of Si 3 N 4 for both thermal and plasma-enhanced processes. ,,− Among them, aminosilanes are particularly attractive because, unlike chlorosilanes, they generate noncorrosive halogenated products. ,, However, thermal processes with chlorosilanes or aminosilanes and either ammonia (NH 3 ) or hydrazine (N 2 H 4 ) require temperatures above 300 °C, which is not acceptable for several applications. ,,,,− Therefore, efforts have turned to plasma-enhanced processes that allow for low-temperature growth. ,,,,, For example, Knoops et al developed a plasma-enhanced atomic layer deposition (PEALD) process using bis( t -butylamino)silane (BTBAS) as a precursor and nitrogen plasma as a coreactant and demonstrated a large temperature window that allowed tunability of the film composition/properties by varying the growth conditions. , Although PEALD silicon nitride growth from aminosilane precursors shows great promise, the underlying reaction mechanisms and relationships between growth conditions and film composition must be understood to develop reliable industrial processes. , Some theoretical attempts have been made to underst...…”