2008
DOI: 10.1002/adma.200701812
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High‐Performance Organic Field‐Effect Transistors with Low‐Cost Copper Electrodes

Abstract: Top‐contact Cu source–drain electrodes are used in high‐ performance organic field‐effect transistors based on pentacene or metal phthalocyanine active layers, as schematically depicted in the figure. Despite the low work function of copper, good hole injection is achieved in these devices because of the formation of an ultrathin CuxO layer at the Cu/organic‐semiconductor interface.

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Cited by 92 publications
(57 citation statements)
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“…The less balanced hole and electron mobilities and possible oxidation to the Cu electrode are likely to be the reasons. 24 Noise margin is another important characteristic of inverters, which describes the range of the valid low/high voltage of the inverter. For an inverter to be operated in a large voltage range, a high noise margin is essential.…”
Section: Resultsmentioning
confidence: 99%
“…The less balanced hole and electron mobilities and possible oxidation to the Cu electrode are likely to be the reasons. 24 Noise margin is another important characteristic of inverters, which describes the range of the valid low/high voltage of the inverter. For an inverter to be operated in a large voltage range, a high noise margin is essential.…”
Section: Resultsmentioning
confidence: 99%
“…Organic thin-fi lm transistors (OTFT) have attracted a lot of attention because of their potential applications in soft, [1][2][3] low-cost, [4][5][6] large-area electrical devices [ 7 , 8 ] and low-voltage driving circuits of soft displays. [9][10][11] Currently, the low mobility of OTFTs is the main challenge for the industrial application of organic devices.…”
Section: Doi: 101002/adma201101178mentioning
confidence: 99%
“…For example, Cu and Ag source-drain electrodes were chemically modified with 7,7,8,8-tetracyanoquinodimethane (TCNQ), when the formation of Cu-TCNQ and Ag-TCNQ reduced the hole injection barrier and improved electrodes/organic layer contact, which reduced contact resistances. Taking pentacene-based OFETs with Ag-TCNQ modified electrodes as an example, the mobility increased from 0.02 to 0.18 cm 2 V −1 s −1 [53]. Gundlach et al [54] demonstrated induced crystallization of an organic layer by electrode interface modification.…”
Section: Interfaces and Their Modificationmentioning
confidence: 99%