High performance supercapacitor electrodes based on spinel NiCo2O4@MWCNT composite with insights from density functional theory simulations

Abstract

In this work, we demonstrated the supercapacitor performance of pristine and composites of spinel NiCo2O4 with a multi-walled carbon nanotube (MWCNT) assembled in a two-electrode cell configuration. Spinel NiCo2O4 and NiCo2O4@MWCNT composites were synthesized via a facile hydrothermal method. The supercapacitive performance of as-synthesized NiCo2O4 and NiCo2O4@MWCNT fabricated on Ni-foam was studied in a 0.5M K2SO4 electrolyte using electrochemical measurement techniques. The symmetric cell configuration of NiCo2O4@MWCNT delivers high specific capacitance (374 F/g at 2 A/g) with high energy density and power density (95 Wh/kg and 3 964 W/kg, respectively) compared to that of pristine NiCo2O4 electrodes (137 F/g at 0.6 A/g). Furthermore, the energy storage performance of the asymmetric cells of NiCo2O4//MWCNT and NiCo2O4@MWCNT//MWCNT was studied to enhance cycling stability (retention of 74.85% over 3000 cycles). We have also theoretically studied the supercapacitance performance of pristine NiCo2O4 and NiCo2O4@SWCNT hybrid structures through its structural and electronic properties using density functional theory predictions. The higher specific capacitance of the NiCo2O4@SWCNT hybrid system with high power density and energy density is supported by the enhanced density of states near the Fermi level and increased quantum capacitance of the hybrid structure. We have theoretically computed the diffusion energy barrier of K+ ions of the K2SO4 electrolyte in the NiCo2O4 layer and compared it with the diffusion barrier for Na+ ions. The lesser diffusion energy barrier for K+ ions in the NiCo2O4 layer contributes toward higher energy storage capacity. Thus, owing to superior electrochemical performance of NiCo2O4 composites with MWCNTs, it can serve as a high-performance electrode material for supercapacitor applications.

Recent Research of NiCo2O4/Carbon Composites for Supercapacitors

“…Hybrids of CNTs/NiCo 2 O 4 were then researched widely. The supercapacitive performance of NiCo 2 O 4 @CNTs was theoretically studied by its structural and electronic properties using density functional theory predictions [60], showing improved density of states near the Fermi level and increased quantum capacitance. This section will discuss the hybrids of NiCo 2 O 4 /CNTs.…”

Supercapacitor Supported by Nickel, Cobalt and Conducting Polymer Based Materials: Design Techniques and Current Advancement

“…NiCo 2 O 4 @ MWCNT demonstrated superior electrochemical performance and demonstrated a good electrode for SCp applications. In addition, using density functional they reveal the enhanced density of states near the Fermi level and increased quantum capacitance of the NiCo 2 O 4 @SWCNT is one of the important reasons for high specific capacitance, high power density and energy density [28]. The PCs use reversible fast faradaic reactions to store electrical charges, which allow them to achieve higher capacitance by at least one order of magnitude than those obtained by EDLCs.…”

“…Recently, PCs received considerable attention due to the one order higher capacitance, higher volumetric capacitance, higher energy density and use of low cost and easily synthesized active material than EDLCs. [28][29][30]. For example, Eskandari et al.…”

Enrichment of the field emission properties of NiCo2O4 nanostructures by UV/ozone treatment

“…Further, ternary metal oxides have drawn impressive attention due to better electronic conductivity. Recently, ternary nickel cobalt oxide (NiCo2O4) has been studied widely because of its high electronic conductivity as it contributes charges from both nickel and cobalt ions [17]. The spinel nickel cobaltite (NiCo2O4) is an intriguing functional metal oxide as an important member of Co-based binary transition metal oxides family [18].…”

“…This 4 feature is of great beneficial for the development of NiCo2O4 as a field emitter. However, it suffers poor electrical conductivity [17].…”