Humidity sensing and water molecule monitoring have become
hot
research topics attributed to their potential applications in monitoring
breathing/physiological conditions of humans, air conditioning in
greenhouses, and soil moisture in agriculture. However, there is a
huge challenge for highly sensitive and precision humidity detection
with wireless and fast responsive capabilities. In this work, a hybrid/synergistic
strategy was proposed using a LiNbO3/SiO2/SiC
heterostructure to generate shear-horizontal (SH) surface acoustic
waves (SAWs) and using a nanocomposite of polyethylenimine-silicon
dioxide nanoparticles (PEI-SiO2 NPs) to form a sensitive
layer, thus achieving an ultrahigh sensitivity of SAW humidity sensors.
Ultrahigh frequencies (1∼15 GHz) of SAW devices were obtained
on a high-velocity heterostructure of LiNbO3/SiO2/SiC. Among the multimodal wave modes, we selected SH waves for humidity
sensing and achieved a high mass-sensitivity of 5383 MHz · mm2 · μg–1. With the PEI-SiO2 NP composite as the sensitive layer, an ultrahigh sensitivity
of 2.02 MHz/% RH was obtained, which is two orders of magnitude higher
than those of the conventional SAW humidity sensors (∼202.5
MHz frequency) within a humidity range of 20–80% RH.