High power density at low electric fields in dopamine modified barium titanate based poly(arylene ether nitrile) based composites

Abstract

Owing to their excellent dielectric properties and energy storage performance, polymer‐based composites have shown great potential in the application of pulse energy storage capacitors and electrostatic capacitors. In this study, BaTiO3 (BT) particles with different sizes were modified with dopamine to prepare core–shell structured BT particles (PDA@BT), and then the poly(arylene ether nitrile) (PEN)‐based PDA@BT/PEN composites were prepared. As a common biological material, dopamine has a variety of functional groups which can be used to improve the compatibility between the fillers and the matrix. Moreover, the movement of the carriers at the interface of the composites is limited and the loss is reduced. The composites with an optimized filler size illustrate a high energy density of 1.37 J/cm3 at 160 kV/mm, which nearly reaches up to the energy density of biaxially oriented polypropylene (BOPP) at low electric field. In addition, the composites have the superior power density of 1.88 MW/cm3 with a fast discharge time of 0.138 μs.

Dielectric study of CoFe2O4/MWCNT/epoxy nanocomposites: Effect of temperature, concentration and irradiation

“…[ 51 ] However, at high frequency, the mobility of charge carriers in CFO/MWCNT/epoxy nanocomposites decreases and hence the dipoles are not able to align their axis parallel to fast changes in frequency with increase in temperature. [ 52 ] Dielectric loss is result of high dielectric constant in dielectric material. The dielectric loss as a function of temperature is shown in Figure 7B.…”