Catal. Sci. Technol.
 2024
DOI: 10.1039/d4cy00894d
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High-pressure in situ X-ray absorption fine structure measurements for hydrogenation of CO2 to methanol over Zn-doped ZrO2

Shohei Tada,
Kazumasa Oshima,
Tastuya Joutsuka
et al.

Abstract: During CO2 hydrogenation under pressurised conditions, slight distortions were observed in the Zn structure. Our DFT calculations revealed that the adsorption of CO2 at Zr4+ sites near Zn species can induce these structural distortions.

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