To understand the
pore-scale processes of asphaltene deposition
during heavy oil recovery by CO2 flooding, a series of
microscopic flooding experiments were conducted in two-dimensional
models under high-temperature (80 °C) and high-pressure (2, 6,
and 10 MPa) conditions. Two different heavy oils, AZ-4 and KD-9 (with
viscosities of 7754 and 19 290 mPa·s, respectively, at
80 °C), were used. In these samples, up to 95% and 85% of oil
viscosity reduction, respectively, could be achieved by CO2 dissolution. During CO2 flooding in the microscopic models,
with increasing fluid pressure (6 and 10 MPa) and CO2 concentrations
(60–80 mol %), both the covered area (17–38%) and the
sizes of the deposited particles (up to 200 μm) became larger.
At 6 MPa, a dynamic between between dissolution and precipitation
was observed in large pores (with diameters of >350 μm).
According
to the solvent dissolution test (heptane and toluene), the deposited
solids comprise both asphaltene and alkane components. Between AZ-4
and KD-9, higher resin/asphaltene ratios tend to reduce asphaltene
deposition during the dissolution of CO2 by stabilizing
the solubility of asphaltene in crude oil. In addition, although permeability
decreased (up to 15%) with increasing pressure (2–10 MPa) and
CO2 concentrations (25–70 mol %), the oil recovery
mostly increased (up to 88.6% with AZ-4). The only decrease in oil
recovery occurred with KD-9, which decreased from 64.7% (6 MPa, with
a CO2 concentration of 69.7%) to 56.1% under 10 MPa and
considerably high CO2 concentrations (79.7 mol %). Compared
with the light oil system, the tested heavy oil shows considerably
improved recovery and less asphaltene deposition during high-concentration
CO2 flooding. Therefore, although CO2 miscibility
can hardly be achieved in heavy oil reservoirs, CO2 is
of great interest due to its high solubility in heavy oil and significant
oil viscosity reduction.