We show that the ͑001͒ surface of GaSb can be cleaned efficiently by exposure to atomic hydrogen at substrate temperatures in the range 400-470°C. This treatment removes carbon and oxygen contamination, leaving a clean, ordered surface with a symmetric ͑1ϫ3͒ reconstruction after a total H 2 dose of approximately 150 kL. An ordered but partially oxidized surface is generated during cleaning, and the removal of this residual oxide is the most difficult part of the process. Auger electron spectroscopy and low energy electron diffraction were used to monitor the chemical cleanliness and the ordering of the surface during the cleaning process, whereas high resolution electron energy loss spectroscopy was used to probe the electronic structure in the near-surface region. The results obtained indicates that this cleaning procedure leaves no residual electronic damage in the near-surface region of the Te-doped (nϳ5ϫ10 17 cm Ϫ3 ) samples of GaSb͑001͒ studied.