High-Resolution Study of Strongly Interacting Vibrational Bands of HDO in the Region 7600–8100 cm−1

High resolution Fourier transform spectrum of HDO in the 7500–8200cm−1 region: revisited

“…Table 1 Deviations between the observed and calculated (SP [1,2]) energy levels for the HDO vibrational states in the considered region Table 2 Rotational energy levels (in cm À1 ) of the (3 0 0), (0 3 1), and (1 1 1) vibrational states of HDO This number should be compared with 135 energy levels obtained in [5] (see Table 1). The observed energy level values are presented in Tables 2 and 3 together with the experimental uncertainties and number of lines used for level determination.…”

“…As will be seen from the forthcoming sections, application of the detailed and accurate theoretical linelist to more extensive and accurate experimental data recorded at a higher resolution and better signal-tonoise ratio resulted in retrieval of large set of new experimental energy levels for the (3 0 0), (0 3 1), and (1 1 1) vibrational states of HDO compared to [5].…”

“…For example, many weak lines were left unassigned in the Fourier transform spectrum recorded and analyzed in the 7600-8100 cm À1 spectral region in [5]. Meanwhile, the prediction power of the SP calculation has proved to be highly helpful in the lineby-line analysis for HDO spectra in many regions [6][7][8][9][10][11].…”

Analysis of the High-Resolution Fourier Spectrum of the ν6 Band of the cis-C2h2d2 Molecule

“…In physical chemistry ethylene is also intensively studied since it can be considered as a prototype for a large number of organic molecules. As can be seen from the foregoing, the high-resolution ethylene spectra have long been the object of close attention (for example, see review presented in [12] and [13][14][15][16][17][18][19][20][21][22][23][24] [37][38][39]) between vibrational states 1> = ( 4 = 1, А 2 ) and |2> = ( 6 = 1, B 1 ) and has the following form [40,41]: …”

Emission Spectrum of Hot HDO in the 380–2190 cm−1 Region

“…Note that we adopt the traditional labeling convention of ¢ for the OD stretching mode and for the OH stretching mode, in spite of the Mulliken convention (24). Other infrared measurements include the detection of several transitions near 1 m by Bykov et al (25)(26) and the 300 -000 and 111 -000 bands by Hu et al (27).…”