Application of spectroscopic
photodetecting technologies in future
innovations such as wearable or integrated electronics will require
miniaturized spectrometers. This can be achieved by using an array
of small-area, wavelength-selective photodetectors. Here, filterless
narrowband photodetectors based on a novel device concept are demonstrated.
The narrowband photoresponse is realized by utilizing nanometer-thick
2,2-((3,4-dimethyl-[2,2:5,2:5,2:5,2-quinquethiophene]-5,5-diyl)bis
(methanylylidene))-dimalononitrile (DCV5T-Me):C60 photoactive
layers (3–6 nm) in a Fabry–Perot cavity. By varying
the cavity thickness, achieved by adjusting the transport layer thicknesses,
we realize continuously tunable detection wavelengths, spanning the
entire visible region (400–700 nm). Most importantly, because
the active layer is only nanometer-thick, position of the active layer
can be adjusted within the cavity. Thus, with an optimized position
of the active layer, the photodetectors exhibit an overtone free,
monochromatic spectral response with a full-width-at-half-maximum
value of 25 nm and an external quantum efficiency over 50%. Although
the absorber layers were kept thin, we realize peak specific detectivities
over 1012 Jones, which is comparable to that of the most
efficient narrowband organic photodetectors lacking spectral tunability
over a broad wavelength range.