2009
DOI: 10.1016/j.ccr.2008.10.015
|View full text |Cite
|
Sign up to set email alerts
|

High-spin Co(II) in monomeric and exchange coupled oligomeric structures: Magnetic and magnetic circular dichroism investigations

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
2

Citation Types

4
38
0

Year Published

2010
2010
2018
2018

Publication Types

Select...
7
2

Relationship

0
9

Authors

Journals

citations
Cited by 39 publications
(42 citation statements)
references
References 51 publications
4
38
0
Order By: Relevance
“…MCD and/or magnetic susceptibility studies of additional µ-1,3-carboxylato, µ-aqua dicobalt(II) complexes have been reported (Schultz et al 1997;Ostrovsky et al 2009). For these complexes, magnetic exchange coupling is always weakly antiferromagnetic or zero.…”
Section: Summary Of Dicobalt(ii) Complex MCD Studiesmentioning
confidence: 96%
See 1 more Smart Citation
“…MCD and/or magnetic susceptibility studies of additional µ-1,3-carboxylato, µ-aqua dicobalt(II) complexes have been reported (Schultz et al 1997;Ostrovsky et al 2009). For these complexes, magnetic exchange coupling is always weakly antiferromagnetic or zero.…”
Section: Summary Of Dicobalt(ii) Complex MCD Studiesmentioning
confidence: 96%
“…Several MCD studies of dinuclear complexes, which serve as structural and spectroscopic models of dinuclear hydrolases, have been reported in recent years (Ostrovsky et al 2006;Johansson et al 2008;Larrabee et al 2008Larrabee et al , 2009Xavier et al 2009;Ostrovsky et al 2009;Daumann et al 2013Daumann et al , 2014. Most of these studies have focussed on dicobalt complexes; the exceptions were Fe(III)Co(II) and Ga(III)Co(II) complexes (Xavier et al 2009).…”
Section: Application 1-mcd Studies Of Co(ii) Model Complexesmentioning
confidence: 97%
“…X-ray analysis has shown that the active structure factors of the corresponding transfer-enzymes are coordinated by the metal (W/Mo) and the sulfur of dithiolene [10,11]. Monomeric complexes containing oxo-ligands exhibit diverse compositions and significant structural versatility [12][13][14][15][16][17]. Herein, we synthesized two complexes, in which W/Mo coordinated with 2,3-DHN forming the core structures, possibly simulating the corresponding tungstoenzyme cofactor and molybdoenzyme cofactor.…”
Section: Introductionmentioning
confidence: 97%
“…However, in some aspects of magnetism, scientists could not completely correlate the macroscopic magnetic properties with microlevel structure. In fact, most of the researches on magnetic properties nowadays focus on the intrinsic properties of the molecule itself such as intramolecular magnetic coupling [2,3] and properties depending on the different metal ions [4,5], but ignore the influence of magnetic behavior caused by external surroundings of a magnetic molecule, namely the micro-environment around the molecule. However, the micro-environment and intermolecular interactions are very important for magnetic properties [6].…”
mentioning
confidence: 99%