Dissimilar welding of duplex stainless steel (DSS) with high-strength low alloy (HSLA) was more complicated since they were utilized in automotive and aerospace design, which needed components with lower weight, higher tensile strength (TS), hardness, corrosion resistance. In this research paper, the main objective was to establish a gas tungsten arc welding process, on a [Formula: see text] angle double groove on both sides of DSS and HSLA, using three different filler metals ER2594, ER70S2 and ER304. The welded surfaces of the specimens were analyzed to assess the microstructural characterization using SEM and Edax, and they were also tested to determine their mechanical and corrosion characteristics. In comparison to microstructural characterization, Mn and Si combination decreased the surface defects in the weldment made by ER2594. The determination of mechanical properties revealed that specimen A produced by ER2594 was superior to other specimens B and C, in terms of yield stress, TS and hardness. Similarly, improved corrosion resistance was achieved by the larger presence of Cr along with Ni in ER2594. In the welded joint, Ni combined with an appropriate proportion of other alloying elements in ER2594 enabled effective control over the ferrite-austenite phase balance, which was crucial for achieving the necessary combination of properties and weldability designed for particular applications. Among the three filler metals, ER2594 showed better microstructure uniformity, enhanced TS, hardness and superior corrosion resistance.