usually divided into two main categories. One category is to use a micro-patterned surface that mimics the bio-structures and the other category is to solely apply nonpatterned adhesive polymers. The adhesion force between different surfaces is generated due to van der Waals forces, [7] capillary forces, [8] mechanical interlocking, [9] covalent bond, [10] and hydrogen bonding. [11] The patterned surfaces can have higher compliance and conformability to various substrate topographies, thus may exhibit better adhesion, compared to non-patterned counterparts. [12] Table 1 summarizes several studies reported in the literature that investigated reversible adhesion or reversible bonding mechanisms, including both patterned and non-patterned methods. The bonding parameters, measured bonding strength, and numbers of bond/debond cycles are listed in the table. Regardless of adhesive media and bonding conditions, the maximum pull-off strength (or bonding strength) is 10 MPa, corresponding to three cycles, and the maximum repeated cycle number is 60, corresponding to 0.53 MPa lap shear strength.The NASA 2015 technology roadmap TA12 [13] proposes lightweight joining concepts by eliminating bolted joints and the NASA 2017 SBIR solicitation [14] describes the ability to reversibly join structural truss units capable of sustaining loads of 100-500 N. In this work, we show a non-patterned reversible bonding solution which shows a combined bonding strength far over 10 MPa, and over 50 bond/debond cycles at both ambient and elevated temperatures, which is potentially of utility for applications such as in the automotive and aerospace industries. To be viable for in-space assembly, adhesive performance at elevated temperatures is a requirement for bonds exposed to the high temperatures that surfaces outside of Earth's atmosphere cyclically sustain when exposed to the Sun. Generally, the schemes described in Table 1 are characterized in terms of bonding strength at room temperature and use polymers that have glass transitions lower than typical values experienced in daylight in Earth orbit.Aromatic thermosetting copolyester (ATSP) is a cured product of cross-linkable aromatic polyester oligomers of various branch coefficients and molecular weight
Aromatic Thermosetting CopolymersReversible bonding is an attractive option for assembly and disassembly of reconfigurable space structures due to the simplicity of the fastening concept. Interchain transesterifications reaction [ITR-a type of dynamic covalent exchange reactions afforded by aromatic thermosetting copolyesters (ATSP)] between two ATSP coatings can successfully be used as a reversible bonding concept, provided that the mode of debonding is completely cohesive (rather than adhesive or delaminatory from metal substrate). An optimization study is carried out on the ITR bonding for which ATSP coating is applied on 7075 aluminum substrates and bond/debond experiments are carried out using a custom-built tool kit. The toolkit enables precise control over bonding pressure, tempe...