1979
DOI: 10.1002/crat.19790140802
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High‐Temperature Crystallization, Composition, Structure, and Certain Properties of Rare‐Earth Gallium Borates

Abstract: Solution-melts based on PbF,-B,O, and Bi,O,-B,O, were used in studying the stability regions and for growth, by way of spontaneous crystallization, of crystals up to 3 iiim in size of twelve cornpounds having the general formula RGI+@&),. All of these compounds are isostructural with carbonate mineral huntite. Their composition is highly dependent on that of the crystallization medium. The facing of the crystals is characterized by a small number of simple forms {lOII}, {1120}, (2IIO}, and less frequently {0… Show more

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Cited by 21 publications
(11 citation statements)
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“…At the same time, as was found quite recently, HoGa 3 (BO 3 ) 4 shows an unusually large magnetoelectric effect [21]. Thus, RE gallium borates deserve to be considered as promising materials not only for luminescent [19] and non-linear laser applications but also for the use in spintronic devices.…”
Section: Introductionmentioning
confidence: 91%
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“…At the same time, as was found quite recently, HoGa 3 (BO 3 ) 4 shows an unusually large magnetoelectric effect [21]. Thus, RE gallium borates deserve to be considered as promising materials not only for luminescent [19] and non-linear laser applications but also for the use in spintronic devices.…”
Section: Introductionmentioning
confidence: 91%
“…RGa-orthoborate crystals with R = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er were obtained by flux method through spontaneous nucleation in accordance with the data on phase relationships in RGa 3 (BO 3 ) 4 -Bi 2 O 3 -B 2 O 3 pseudo-ternary systems [19]. As an example, Fig.…”
Section: Crystal Growthmentioning
confidence: 98%
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“…(8) The crystal lattice interaction energy U is changed according to the change of the interaction energy of cations, assuming that the interaction energy of Yb 3+ with lattice is less than that of Er 3+ , and that of Al 3+ is less than that of Ga 3+ , 6 At first sight, the relation of energies (9) between the compositions of 7-2 and 5-1 is not completely correct, because the cations in both positions were changed. (8) The crystal lattice interaction energy U is changed according to the change of the interaction energy of cations, assuming that the interaction energy of Yb 3+ with lattice is less than that of Er 3+ , and that of Al 3+ is less than that of Ga 3+ , 6 At first sight, the relation of energies (9) between the compositions of 7-2 and 5-1 is not completely correct, because the cations in both positions were changed.…”
Section: 2mentioning
confidence: 99%
“…Гораздо менее изучены галлиевые бораты из семейства хантитов. Имеются единичные работы по изучению кристаллической структуры, условий роста [3,[19][20][21][22] и спектроскопических свойств [22]. В частности, в работе [22]…”
Section: Introductionunclassified