The present study focuses on the synthesis of three distinct WC‐HEA hard alloys using the SPS method, employing three different grades of tungsten carbide with varying particle sizes. Subsequently, an investigation was conducted to analyze the influence of WC particle size on the microstructure and properties of WC‐10CoCrFeNiAl hard alloys. Additionally, the dual‐scale WC‐10CoCrFeNiAl hard alloy was synthesized through a combination of two distinct WC particles, and an investigation was conducted to assess the influence of small particle size WC addition content on both the microstructure and properties of this advanced alloy. The results indicate that a reduction in the particle size of WC leads to an increase in hardness, while exhibiting a non‐monotonic change in fracture toughness of WC‐10CoCrFeNiAl hard alloy. The presence of smaller WC particles promotes the formation of N7C3 and η phase (M3W9C4), which compromises its toughness while simultaneously enhancing its hardness. The mechanical properties are optimized when the particle size of WC is approximately 1μm (HV30:17.96 GPa, KIC:12.3 MPa.m1/2). Investigation on the dual‐scale WC‐10CoCrFeNiAl hard alloy further reveals that the incorporation of fine WC particles significantly enhances hardness while compromising fracture toughness. When the content of small particle WC reaches 25 wt.%, the mechanical properties of the dual‐scale hard alloy are optimized (HV30:18.8 GPa, KIC:11.1 MPa.m1/2).This article is protected by copyright. All rights reserved.