Concentrating Solar Power (CSP) plants allow green and dispatchable electricity production. Novel process schemes combining high solar-to-electric performance with an optimum integration of cheap and environmentally friendly storage systems are key for the massive deployment of solar plants. The integration of solar energy in combined cycles, as the most efficient thermal power cycles, is gaining momentum. Combined cycles require high temperature (typically higher than 1000ºC), which does not allow the operation of the solar combined cycle at night by integrating the current commercial thermal storage systems (molten salts-based system maximum temperature is limited to ~600ºC). Thus, solar power share in current Integrated Solar Combined Cycles (ISCC) is typically lower than 20%, while natural gas is used to provide most of the thermal power required. Under this scenario, the promising Thermochemical Energy Storage (TCES), capable of operating at high temperatures with high yields, provide a high potential to increase the solar share since the solar energy stored can be released at temperatures above 1000ºC, allowing electricity production in a combined cycle even without solar radiation or other fuel input. Among TCES systems to be integrated into CSP plants, the Calcium-Looping (CaL) process is gaining momentum due to a high energy density, abundant and cheap raw material (limestone) and its high turning temperature. This paper proposes the novel concept of a High Temperature Storage Solar Combined Cycle (HTSSCC) based on the integration of a TCES system. A model has been developed for simulating the proposed plant. Results show overall plant efficiencies higher than 45% (excluding solar side losses), which suggests a high potential for the development of this novel integration.