2021
DOI: 10.1021/acs.energyfuels.1c03442
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High-Temperature Pyrolysis and Combustion of C5–C19 Fatty Acid Methyl Esters (FAMEs): A Lumped Kinetic Modeling Study

Abstract: In the effort to mitigate the depletion of fossil fuels and climate change, biodiesels are considered to be one of the most suitable substitutes for petro-diesel in compression ignition engine applications. As a follow up to prior modeling studies for gasoline and jet surrogate fuel components (Zhang, X.; Mani Sarathy, S. Fuel, 2021, 286, 119361), this work proposes a lumped kinetic model for both saturated and unsaturated C5–C19 fatty acid methyl esters (FAMEs) based on the same methodology. The present lumpe… Show more

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Cited by 12 publications
(4 citation statements)
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“…Another paper focused on the chemical kinetics of methyl esters, the type of components frequently found in biodiesel. Xiaoyuan and Sarathy proposed a lumped kinetic model for combustion of 52 saturated, monounsaturated, and polyunsaturated C 5 –C 19 fatty acid methyl esters . The last paper in this group described spray vaporization characteristics of alcohols and esters.…”
Section: Combustion Of Alcohols and Estersmentioning
confidence: 99%
See 1 more Smart Citation
“…Another paper focused on the chemical kinetics of methyl esters, the type of components frequently found in biodiesel. Xiaoyuan and Sarathy proposed a lumped kinetic model for combustion of 52 saturated, monounsaturated, and polyunsaturated C 5 –C 19 fatty acid methyl esters . The last paper in this group described spray vaporization characteristics of alcohols and esters.…”
Section: Combustion Of Alcohols and Estersmentioning
confidence: 99%
“…Specifically, they compared how laminar flame speeds and ignition delay times vary with the content of both alcohols. Lokachari et al 14 16 The last paper in this group described spray vaporization characteristics of alcohols and esters. Specifically, Singh et al 17 investigated acetone, ethanol, and biodiesel spray flames to link the spray characteristics and flame stability.…”
Section: ■ Combustion Of Alcohols and Estersmentioning
confidence: 99%
“…Recent years have seen a growing interest in the development of a broad portfolio of bioderived compounds as alternatives to the traditional fossil fuel-derived chemicals. Naturally available vegetable oils (VOs) are a major feedstock for biorefineries, , leading to a variety of so-called oleochemicals with ramifications in the synthesis of surfactants, , lubricants, polymers, and other useful compounds such as carbonated vegetable oils. , An important class of oleochemicals is represented by functional olefins such as 9-decenoic acid methyl ester (9-DAME), which is a valuable fine chemical with potential application for the preparation of biodiesel surrogates, , bioaviation fuel, and as a starting material for the preparation of diverse functional compounds. 9-DAME can be obtained from the ethenolysis (metathetic cleavage with ethene) of oleic fatty acid ester chains derived from VO transesterification leading to the formation of an equivalent of 1-decene, a valuable α-olefin used for the synthesis of polymers and food additives just to cite some applications. The catalytic ethenolysis of oleic fatty acids to produce 9-DAME and 1-decene has been studied in the past. ,, Homogeneous ruthenium alkylidene complexes are powerful catalysts for the ethenolysis of methyl oleate, showing high catalytic turnover at moderate methyl oleate conversion under 10 bar ethylene. , However, given the high cost of ruthenium-based catalysts and the geographically restricted availability and critical resource status of ruthenium, there has been an increasing interest toward alkylidene complexes of inexpensive and ubiquitously available metals such as molybdenum. , A homogeneous molybdenum imido alkylidene monoaryloxide monopyrrolide complex was reported to carry out the ethenolysis of methyl oleate with high yields and selectivity at room temperature under 10 bar ethylene .…”
Section: Introductionmentioning
confidence: 99%
“… 1 4 Naturally available vegetable oils (VOs) are a major feedstock for biorefineries, 5 , 6 leading to a variety of so-called oleochemicals with ramifications in the synthesis of surfactants, 7 , 8 lubricants, 9 polymers, 10 13 and other useful compounds such as carbonated vegetable oils. 12 , 14 17 An important class of oleochemicals is represented by functional olefins such as 9-decenoic acid methyl ester (9-DAME), which is a valuable fine chemical with potential application for the preparation of biodiesel surrogates, 18 , 19 bioaviation fuel, 20 and as a starting material for the preparation of diverse functional compounds. 21 23 9-DAME can be obtained from the ethenolysis (metathetic cleavage with ethene) 24 of oleic fatty acid ester chains derived from VO transesterification leading to the formation of an equivalent of 1-decene, a valuable α-olefin used for the synthesis of polymers 25 and food additives 26 just to cite some applications.…”
Section: Introductionmentioning
confidence: 99%