High‐Throughput Heterogeneous Catalytic Science

Hendershot, Reed J.; Snively, Christopher M.; Lauterbach, Jochen A.

doi:10.1002/chem.200400613

Cited by 55 publications

(16 citation statements)

References 96 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In this respect, catalyst development studies involve examining a large number of catalysts, for which recent advances in high-throughput testing have attracted considerable attention [82][83][84][85][86][87]. Catalyst development through the testing of a wide range of materials was first practiced in 1909 by Mittasch at BASF who, according to Timm [88], issued the following directive to his team who at the time were developing the synthesis of ammonia:…”

Section: Catalyst Developmentmentioning

confidence: 99%

Principles of Heterogeneous Catalysis

Dumesic¹,

Huber²,

Boudart³

1996

Handbook of Heterogeneous Catalysis

133

166

View full text Add to dashboard Cite

The sections in this article are Introduction Definitions of Catalysis and Turnover Steps in a Heterogeneous Catalytic Reaction Desired Characteristics of a Catalyst Reaction Schemes and Adsorbed Species Conditions for Catalyst Optimality Catalyst Design Catalyst Development Bridging Gaps in Heterogeneous Catalysis A Philosophical Note

show abstract

Section: Catalyst Developmentmentioning

confidence: 99%

Principles of Heterogeneous Catalysis

Dumesic¹,

Huber²,

Boudart³

1996

Handbook of Heterogeneous Catalysis

133

166

View full text Add to dashboard Cite

show abstract

“…In this work, a high-throughput methodology is applied for the discovery and optimization of novel catalyst formulations to convert readily available hydrocarbon-based JP-8 fuel directly into a lighter hydrocarbon product, such as LPG, suitable for portable power applications. Within the past decade, the high-throughput approach has become widespread in the field of catalysis [2][3][4]. This project offers the chance for high-throughput to prove itself on a short time scale due to the need to develop a new material in a matter of months for a targeted application.…”

Section: Introductionmentioning

confidence: 99%

High-Throughput Screening of Catalytic Materials for JP-8 Fuel Cracking to Liquefied Petroleum Gas

et al. 2012

Self Cite

View full text Add to dashboard Cite

A high-throughput methodology is applied for the discovery and optimization of novel catalyst formulations to convert readily available hydrocarbon-based JP-8 fuel directly into a lighter hydrocarbon product suitable for portable power applications utilizing LPG-powered fuel cells. In addition to catalytic cracking challenges, JP-8 cracking poses other challenges including high sulfur content (up to 3,000 ppmw) and significant concentration of aromatics, which are precursors to coking. An existing 16-channel high-throughput reactor system was modified for the JP-8 catalytic cracking studies. The catalyst support material was of primary importance in determining cracking activity. Alumina-based catalytic materials demonstrate the greatest activity for conversion of JP-8 to LPG during catalytic cracking at reactor temperatures above 600 o C. This is attributed to the importance of acidic reaction sites within the structure of the catalytic support. The addition of noble metals to the alumina-based materials does not yield significant improvements in JP-8 conversion.

show abstract

“…High-throughput analytical methods [1] based on IR thermography, [2] fluorescence, [3] colorimetric assays, [4] immunoassay, [5] mass spectrometry (MS) analysis, [6] have been developed to monitor chemical reactions and catalysts. These methods are very powerful and are well suited for the screening of large numbers of similar reactions; however, they are less proficient for evaluating multistep organic reactions.…”

Section: Introductionmentioning

confidence: 99%

Trimethoxyarene as a Highly Ionizable Tag for Reaction Analysis by Atmospheric Pressure Photoionization Mass Spectrometry (APPI/MS): Exploration of Heterocyclic Synthesis

Catala¹,

Colas

Schaeffer

et al. 2011

Eur J Org Chem

View full text Add to dashboard Cite

A mass spectrometry (MS) method was developed to rapidly analyze crude reaction mixtures. This method relies on highly effective ionization by atmospheric pressure photoionization (APPI) of molecules with a prosthetic trimethoxyarene (TMOA) residue. In a crude reaction mixture, products resulting from the reaction of the TMOA-labeled substrate will be selectively ionized to afford an easily readable mass

show abstract

High‐Throughput Heterogeneous Catalytic Science

Cited by 55 publications

References 96 publications

Principles of Heterogeneous Catalysis

Principles of Heterogeneous Catalysis

High-Throughput Screening of Catalytic Materials for JP-8 Fuel Cracking to Liquefied Petroleum Gas

Trimethoxyarene as a Highly Ionizable Tag for Reaction Analysis by Atmospheric Pressure Photoionization Mass Spectrometry (APPI/MS): Exploration of Heterocyclic Synthesis

Contact Info

Product

Resources

About