High‐Throughput Synthesis and Screening of Combinatorial Heterogeneous Catalyst Libraries

Cong, Peijun; Doolen, Robert D.; Fan, Qun; Giaquinta, Daniel M.; Guan, Shenheng; McFarland, Eric W.; Poojary, Damodara M.; Self, Kyle; Turner, Howard W.; Weinberg, W. H.

doi:10.1002/(sici)1521-3773(19990215)38:4<483::aid-anie483>3.0.co;2-#

Cited by 231 publications

(84 citation statements)

References 11 publications

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“…We select here, somewhat arbitrarily, HTE studies published early in 2014, so immediately prior to this conference. HTE has been applied with some success to the discovery and development of both homogeneous and heterogeneous catalysts [4][5][6][7][8][9][10][11][12][13][14][15][16]. As several recent examples are also discussed elsewhere in this volume, we look here to examples from other fields.…”

Section: Recent Examples In Materials For Energy Applicationsmentioning

confidence: 99%

High Throughput Experimentation (HTE) Directed to the Discovery, Characterization and Evaluation of Materials

Newsam¹

2014

Oil Gas Sci. Technol. – Rev. IFP Energies nouvelles

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Cet article fait partie du dossier thématique ci-dessous publié dans la revue OGST, Vol. 70, n°2, et téléchargeable ici D o s s i e rOil & Gas Science and Technology -Rev. IFP Energies nouvelles, Vol. 70 (2015), No. 3, Copyright © 2015, IFP Energies nouvelles > Editorial -Towards the Laboratory of the Future for the Factory of the FutureÉditorial -Vers le laboratoire du futur pour construire l'usine du futur Abstract -We attempt to take a strategic view of the development and application of HTE techniques across a broad spectrum of chemical, material and earth sciences, looking for unifying assumptions and approaches. We consider why much of the development of HTE technologies and techniques, as well as the majority of their application, have taken place in industry or in institutes or centers working closely with industry. And we look for commonalities and synergies across diverse HTE application areas, taking examples from the energy, catalysis, formulations and biotechnology fields.

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Section: Recent Examples In Materials For Energy Applicationsmentioning

confidence: 99%

High Throughput Experimentation (HTE) Directed to the Discovery, Characterization and Evaluation of Materials

Newsam¹

2014

Oil Gas Sci. Technol. – Rev. IFP Energies nouvelles

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“…Senkan developed a REMPI (resonance enhanced multi photon ionization) detector for the evaluation of the hydrogenation of 1-hexene 18) . Cong et al used a q-mass spectrometer for product quantifi cation in the oxidative dehydration of ethane 19) . Snively and Lauterbach have developed a parallel FT-IR (Fourier transform infrared spectroscopy) with 2-D detectors 20) .…”

Section: Gas Sensor System For High Throughput Screening Of Heteromentioning

confidence: 99%

Utilization of Combinatorial Method and High Throughput Experimentation for Development of Heterogeneous Catalysts

Yamada

Kobayashi

2006

J. Jpn. Petrol. Inst.

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The combinatorial method and high throughput experimentation have been applied to catalysis development in the last decade. Here we describe equipment for catalyst preparation, catalysis evaluation and product analysis with a gas sensor system. High throughput experimentation using these devices has allowed us to optimize catalyst composition with stochastic methods such as the genetic algorithm. The improvement of propane selective oxidation catalysis is described. High throughput experimentation allowed the construction of a database for elemental reactions. We have developed novel catalysts for ethanol steam-reforming catalysts and a dimethyl ether steam-reforming catalyst by combining good catalysts for each elemental reaction. Our new concept of Materiomics is introduced as a promising method for material science based on combinatorial technology.

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“…Many other successful examples of high-throughput based material development have been reported [6]. Most efforts have been spent on accelerating material synthesis and testing [7][8][9] by optimization of the catalyst library using e.g., the split and pool method [10], Design of Experiments (DoE) [11] or an evolutionary algorithm [12]. Only few have tried to develop more comprehensive strategies for catalyst development [13,14].…”

Section: Introductionmentioning

confidence: 99%

Information-Driven Catalyst Design Based on High-Throughput Intrinsic Kinetics

et al. 2015

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Abstract:A novel methodology is presented for more comprehensive catalyst development by maximizing the acquired information rather than relying on statistical methods or tedious, elaborate experimental testing. Two dedicated high-throughput kinetics (HTK) set-ups are employed to achieve this objective, i.e., a screening (HTK-S) and a mechanistic investigation one (HTK-MI). While the former aims at evaluating a wide range of candidate catalysts, a limited selection is more elaborately investigated in the latter one. It allows focusing on an in-depth mechanistic analysis of the reaction mechanism resulting in so called "kinetic" descriptors and on the effect of key catalysts properties, also denoted as "catalyst" descriptors, on the catalyst performance. Both types of descriptors are integrated into a (micro)kinetic model that allows a reliable extrapolation towards operating conditions and catalyst properties beyond those included in the high-throughput testing. A case study on ethanol conversion to hydrocarbons is employed to illustrate the concept behind this methodology. The methodology is believed to be particularly useful for potentially large-scale chemical reactions.

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High‐Throughput Synthesis and Screening of Combinatorial Heterogeneous Catalyst Libraries

Cited by 231 publications

References 11 publications

High Throughput Experimentation (HTE) Directed to the Discovery, Characterization and Evaluation of Materials

High Throughput Experimentation (HTE) Directed to the Discovery, Characterization and Evaluation of Materials

Utilization of Combinatorial Method and High Throughput Experimentation for Development of Heterogeneous Catalysts

Information-Driven Catalyst Design Based on High-Throughput Intrinsic Kinetics

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