2022
DOI: 10.1002/ange.202114353
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Highly Accurate Synthesis of Quasi‐sub‐nanoparticles by Dendron‐assembled Supramolecular Templates

Abstract: have been predicted to exhibit unique properties originating from the gray structures considered both bulk solids and molecules, while their synthesis is extremely difficult. The present study describes a new template synthesis method for quasi-subnanosized materials using a combination of coordination chemistry and polymer chemistry. Utilizing self-assembly of guest basic phenylazomethine dendron units onto host acidic core units with six tritylium cations, the dendron-assembled supramolecules were constructe… Show more

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Cited by 2 publications
(2 citation statements)
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“…2). 12 As a supramolecular capsule, a dendron-assembled supramolecule was constructed by self-assembling a basic phenylazomethine dendron unit into a host acidic core unit with six tritylium cations. Multiple acidic rhodium salts are accumulated in the basic ligand of this supramolecular capsule, which enables the precise synthesis of rhodium particles by multinuclear complex formation.…”
Section: Nanoarchitectonics From Atomsmentioning
confidence: 99%
“…2). 12 As a supramolecular capsule, a dendron-assembled supramolecule was constructed by self-assembling a basic phenylazomethine dendron unit into a host acidic core unit with six tritylium cations. Multiple acidic rhodium salts are accumulated in the basic ligand of this supramolecular capsule, which enables the precise synthesis of rhodium particles by multinuclear complex formation.…”
Section: Nanoarchitectonics From Atomsmentioning
confidence: 99%
“…There potential applications of dendrimer in a number of different areas ranging from diagnostics, nanomedicine, nanotechnology to cosmetics 2 due to their properties. The dendritic architecture provides a multivalent surface, which can be used for amplifying weak interactions between a ligand and a receptor as demonstrated with glycodendrimers 3,4 , for vaccines (MAPs) [5][6][7][8] or as artificial receptors [9][10][11][12] . The nanometer size of dendrimers allows targeting of cancer tumors using the enhanced permeation retention-effect (epr) [13][14][15][16] .…”
mentioning
confidence: 99%