Highly active NiFe LDH anchoring on cobalt carbonate hydroxide for efficient electrocatalytic 5-hydroxymethylfurfural oxidation towards 2,5-furandicarboxylic acid

Dhanasmoro, Lintang; Li, Oi Lun

doi:10.1039/d3nj01836a

Cited by 6 publications

(1 citation statement)

References 54 publications

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“…The high yield of FDCA was 99.3%, the FE was as high as 98.9%, and the FE remained at 96.7% after six consecutive electrolytic cycles. Similarly, Li and co-workers developed an NiFe LDH/CoCH/NF electrocatalyst by a two-step hydrothermal method [68]. Compared with NiFe LDH/NF and CoCH/NF, the coupled NiFe LDH/CoCH/NF catalyst had a unique folded nanosheet structure and a higher electrochemical active surface area, faster electron transfer kinetics, and more active sites.…”

Section: Hydroxidesmentioning

confidence: 99%

Recent Advances in Electrocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Heterogeneous Catalysts

Ma,

Wang,

et al. 2024

Catalysts

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The utilization and development of biomass resources is an efficient solution to mitigate the fossil energy crisis. Based on the advantages of mild reaction conditions, rapid reaction, and high conversion, the synthesis of 2,5-furandicarboxylic acid (FDCA) by the electrocatalytic oxidation of 5-hydroxymethylfurfural (HMFOR) has attracted considerable attention. This review will summarize the recent advances of HMFOR to FDCA, including the reaction pathway and mechanism, as well as the catalytic performance of various heterogeneous electrocatalysts. The challenges and prospects for HMFOR are also focused on. Finally, it is expected that this work may provide guidance for the design of high-efficiency electrocatalysts and thereby accelerate the industrialization process of biomass utilization.

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Section: Hydroxidesmentioning

confidence: 99%

Recent Advances in Electrocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Heterogeneous Catalysts

Ma,

Wang,

et al. 2024

Catalysts

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Tailored Engineering of Layered Double Hydroxide Catalysts for Biomass Valorization: A Way Towards Waste to Wealth

Kumar,

Choudhary,

Sharma

et al. 2024

ChemSusChem

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Layered double hydroxides (LDH) have significant attention in recent times due to their unique characteristic properties, including layered structure, variable compositions, tunable acidity and basicity, memory effect, and their ability to transform into various kinds of catalysts, which make them desirable for various types of catalytic applications, such as electrocatalysis, photocatalysis, and thermocatalysis. In addition, the upcycling of lignocellulose biomass and its derived compounds has emerged as a promising strategy for the synthesis of valuable products and fine chemicals. The current review focuses on recent advancements in LDH‐based catalysts for biomass conversion reactions. Specifically, this review highlights the structural features and advantages of LDH and LDH‐derived catalysts for biomass conversion reactions, followed by a detailed summary of the different synthesis methods and different strategies used to tailor their properties. Subsequently, LDH‐based catalysts for hydrogenation, oxidation, coupling, and isomerization reactions of biomass‐derived molecules are critically summarized in a very detailed manner. The review concludes with a discussion on future research directions in this field which anticipates that further exploration of LDH‐based catalysts and integration of cutting‐edge technologies into biomass conversion reactions hold promise for addressing future energy challenges, potentially leading to a carbon‐neutral or carbon‐positive future.

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Towards Sustainable Production of Polybutylene Adipate Terephthalate: Non‐Biological Catalytic Syntheses of Biomass‐Derived Constituents

Lee,

Park,

Fai Tsang

et al. 2024

ChemSusChem

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Renewable chemicals, which are made from renewable resources such as biomass, have attracted significant interest as substitutes for natural gas‐ or petroleum‐derived chemicals to enhance the sustainability of the chemical and petrochemical industries. Polybutylene adipate terephthalate (PBAT), which is a copolyester of 1,4‐butanediol (1,4‐BDO), adipic acid (AA), and dimethyl terephthalate (DMT) or terephthalic acid (TPA), has garnered significant interest as a biodegradable polymer. This study assesses the non‐biological production of PBAT monomers from biomass feedstocks via heterogeneous catalytic reactions. The biomass‐based catalytic routes to each monomer are analyzed and compared to conventional routes. Although no fully commercialized catalytic processes for direct conversion of biomass into 1,4‐BDO, AA, DMT, and TPA are available, emerging and promising catalytic routes have been proposed. The proposed biomass‐based catalytic pathways toward 1,4‐BDO, AA, DMT, and TPA are not yet fully competitive with conventional fossil fuel‐based pathways mainly due to high feedstock prices and the existence of other alternatives. However, given continuous technological advances in the renewable production of PBAT monomers, bio‐based PBAT should be economically viable in the near future.

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Highly active NiFe LDH anchoring on cobalt carbonate hydroxide for efficient electrocatalytic 5-hydroxymethylfurfural oxidation towards 2,5-furandicarboxylic acid

Abstract: One viable approach in reducing reliance on fossil fuels is the utilization of value-added chemicals through the conversion of biomass. In recent years, significant attention has been directed toward the...

Cited by 6 publications

References 54 publications

Recent Advances in Electrocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Heterogeneous Catalysts

Recent Advances in Electrocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Heterogeneous Catalysts

Tailored Engineering of Layered Double Hydroxide Catalysts for Biomass Valorization: A Way Towards Waste to Wealth

Towards Sustainable Production of Polybutylene Adipate Terephthalate: Non‐Biological Catalytic Syntheses of Biomass‐Derived Constituents

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