In this research, waterborne polyurethane (WPU) nanocomposites incorporated with MgAl-NO 3 LDH layered double hydroxide (LDH) and phytic acid intercalated LDH (PA-LDH) nanostructures were prepared as novel environmental-friendly corrosion protective coatings. Fourier-transform infrared spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis, field emission scanning electron microscope (SEM), and high-resolution transmission electron microscopy analysis confirmed the prosperous preparation of LDHs nanosheets. Moreover, structural, thermal, thermo-mechanical, and morphological investigations of prepared WPU/LDHs films were also evaluated.