Highly exfoliated NiPS3 nanosheets as efficient electrocatalyst for high yield ammonia production

Nitrogen reduction reaction energy and pathways in metal-zeolites: deep learning and explainable machine learning with local acidity and hydrogen bonding features

“…11,12,60,61 In Table S12, † some catalysts have realized ammonia production and achieved high Faraday efficiency (FE) for the conversion from N 2 to NH 3 in experiment, although the desorption step (NH 3 * to NH 3 ) required 0.94-1.73 eV energy inputs. [62][63][64][65][66] In metal-zeolites studied in this work, the NH 3 desorption step free energies were 2.12, 1.65, and 1.46 eV for Ti-, Co-, and Nb-zeolites, respectively. The accumulated energy in previous steps may be attributed to the good catalytic performance.…”

NaCl template-assisted construction of a CoP–MoP heterostructured electrocatalyst for electrocatalytic nitrogen reduction

“…Furthermore, the good interfacial synergistic effects accelerate the electron transfer from the MoP to CoP, and a large number of electrons accumulate at the CoP interface to participate in the NRR. 50…”

“…Furthermore, the good interfacial synergistic effects accelerate the electron transfer from the MoP to CoP, and a large number of electrons accumulate at the CoP interface to participate in the NRR. 50 Furthermore, the microstructure of the CoP-MoP heterostructured catalyst was characterized by scanning electron microscopy (SEM). The CoP-MoP obtained by NaCl templated construction exhibits an evident layered structure with curled edges, which facilitates the exposure of active sites (Fig.…”

Emerging two-dimensional materials for the electrocatalytic nitrogen reduction reaction to yield ammonia

“…7a). 66 However, this work did not exclude the interference of contamination on the experimental results through experiments such as isotope labeling. The control of sulfur vacancies (SVs) was achieved by adjusting the phosphorus doping level, as demonstrated by electron paramagnetic resonance (EPR) (Fig.…”