Highly ordered hierarchical porous carbon derived from biomass waste mangosteen peel as superior cathode material for high performance supercapacitor

Yang, Viengkham; Senthil, Raja Arumugam; Pan, Junqing; Khan, Abrar; Osman, Sedahmed; Wang, Liren; Jiang, Wenchao; Sun, Yanzhi

doi:10.1016/j.jelechem.2019.113616

Cited by 133 publications

(44 citation statements)

References 68 publications

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“…The (002) plane corresponds to a hexagonal configuration, whereas the (100) diffraction is the in-plane graphitic structure of activated carbon. Other biomassbased carbon materials demonstrating similar behavior include durian shell, 43 banana stem 44 and mangosteen, 20 although the XRD peak broadness was observed to have largely reduced from CP-0.5 to CP-0.9. This is indicative of a structure transition from amorphous to graphitic, following the addition of ZnCl 2.…”

Section: Resultsmentioning

confidence: 99%

“…Meanwhile numerous reports have shown the potential for adopting agricultural and agro‐industrial wastes in the development of hierarchical pores and modification of the surface morphology of supercapacitor electrodes 17–19 . This was recently demonstrated in a study by Yang et al ., which reported on the modification of carbon obtained from mangosteen waste, using carbonization methods, followed by activation with sodium hydroxide (NaOH) 20 . The resulting material possessed a surface area of 2623 m 2 g −1 , with excellent specific capacitance of 357 F g −1 .…”

Section: Introductionmentioning

confidence: 99%

“…[17][18][19] This was recently demonstrated in a study by Yang et al, which reported on the modification of carbon obtained from mangosteen waste, using carbonization methods, followed by activation with sodium hydroxide (NaOH). 20 The resulting material possessed a surface area of 2623 m 2 g −1 , with excellent specific capacitance of 357 F g −1 . Similar results were shown by carbon from pitaya waste and basil seed produced using potassium hydroxide (KOH) activation, which gave a surface area of 1178.3-1870 m 2 g −1 , and specific capacitance of 255-464 F g −1.…”

Section: Introductionmentioning

confidence: 99%

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A rod‐like mesoporous carbon derived from agro‐industrial cassava petiole waste for supercapacitor application

Taer

Apriwandi

Dalimunthe

et al. 2020

J of Chemical Tech & Biotech

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BACKGROUND Agro‐industrial co‐products rich in lignocellulose, for example cassava petiole (CP) waste, have high potential as sources of porous carbon materials, alongside other impressive advantages, including ease of acquisition, abundance and availability, renewability and low cost. This work shows the successful treatment of mesoporous carbon with rod‐like structure derived from agro‐industrial CP waste carbonized and physically activated by direct one‐stage integrated pyrolysis using a zinc chloride (ZnCl2) activator agent, in the production of a supercapacitor electrode for energy storage. The ZnCl2 was tested at varying concentrations, including 0.5, 0.7 and 0.9 mol L–1. The surface morphology, chemical content, surface area and porous size distribution were evaluated to determine the physical properties of activated carbon, and a cyclic voltammetry method was used to assess the electrochemical characteristics using a two‐electrode system in 1 mol L–1 H2SO4 as an electrolyte. RESULTS The porous carbon obtained displayed a rod‐like morphology structure, featuring numerous hierarchical tuneable and well‐confirmed micropores and mesopores. This monolithic material contained predominantly C (87.85%), demonstrating a maximum surface area of 759.816 m2 g−1 at 0.9 mol L–1 concentration. Furthermore, the highest specific capacitance reached was 193 F g−1 at 0.7 mol L–1, with maximum energy and power densities of 26.90 Wh kg−1 and 96.94 W kg−1, respectively. CONCLUSION The novel rod‐like mesoporous carbon derived from CP waste produced using a facile, cost‐effective and sustainable method, without metal–organic framework or templates, shows great potential as an electrode material for enhanced supercapacitor performance. © 2020 Society of Chemical Industry (SCI)

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Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

A rod‐like mesoporous carbon derived from agro‐industrial cassava petiole waste for supercapacitor application

Taer

Apriwandi

Dalimunthe

et al. 2020

J of Chemical Tech & Biotech

View full text Add to dashboard Cite

show abstract

“…Generally, the XRD pattern show the presence of strong peaks in the reflection planes [002] and [100]. Furthermore, it correlates with 2θ angles approximately 22-25° and 43-45° and this showed that all samples impregnated with the activating agent have an amorphous carbon structure [33,34]. The reflection plane [002] at 22-25° indicates a hexagonal configuration of porous carbon and the existence of a small amount of graphite microcrystalline structure [35].…”

Section: Microstructure Featuresmentioning

confidence: 99%

Nanofiber-enrich activated carbon coin derived from tofu dregs as electrode materials for supercapacitor

Taer

Apriwandi

Hasanah

et al. 2021

CST

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In this study, the activated carbon with enriched nanofiber obtained from free-binder materials. It was conducted tofu dregs carbon nanofiber as electrode material for supercapacitor without the addition of pVdF/PTFE. The chemical impregnation of NaOH, ZnCl2 and H3PO4 at high-temperature pyrolysis in an N2-CO2 environment converted the tofu dregs into carbon coin. Subsequently, the physical properties including, microcrystalline, morphology, element analysis, and electrochemical properties of specific capacitance were investigated. The morphological structure of activated carbon showed high nanofiber density and was decorated by sponge-like pores. In addition, the nanofiber contains oxygen content of 12.70% which can act as self-doping due to the pseudo-capacitance properties. Furthermore, the two-electrode system obtained a specific capacitance of 163 F g-1 in 1 M H2SO4 electrolyte. The results showed that tofu dregs-based activated carbon coins are sustainable and efficient to obtain high-dense nanofiber structure as electrode materials for energy storage applications.

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“…Nowadays, the preparation of porous carbon materials has attracted much attention due to their interesting properties such as excellent electrical conductivity, high surface areas and high pore volumes, and good chemical, thermal, and mechanical stabilities [ 55 , 56 , 57 , 58 , 59 ]. Therefore, porous carbonaceous materials have been applied in many real-life applications, for example catalysis, gas separation, gas capture, energy storage in supercapacitors and batteries, fuel cells, water treatment and purification, and electromagnetic interface shielding [ 60 , 61 , 62 , 63 , 64 ]. As reported, the preparation of porous carbonaceous materials with high surface area and excellent porosity nature can be achieved by chemical activation for many polymers’ precursors, for example conjugated microporous polymers (CMPs), metal-organic frameworks (MOFs), HCPs, and porous aromatic frameworks (PAFs) [ 62 , 63 , 64 ].…”

Section: Introductionmentioning

confidence: 99%

Meso/Microporous Carbons from Conjugated Hyper-Crosslinked Polymers Based on Tetraphenylethene for High-Performance CO2 Capture and Supercapacitor

Mohamed

Ahmed

et al. 2021

Molecules

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In this study, we successfully synthesized two types of meso/microporous carbon materials through the carbonization and potassium hydroxide (KOH) activation for two different kinds of hyper-crosslinked polymers of TPE-CPOP1 and TPE-CPOP2, which were synthesized by using Friedel–Crafts reaction of tetraphenylethene (TPE) monomer with or without cyanuric chloride in the presence of AlCl3 as a catalyst. The resultant porous carbon materials exhibited the high specific area (up to 1100 m2 g−1), total pore volume, good thermal stability, and amorphous character based on thermogravimetric (TGA), N2 adsoprtion/desorption, and powder X-ray diffraction (PXRD) analyses. The as-prepared TPE-CPOP1 after thermal treatment at 800 °C (TPE-CPOP1-800) displayed excellent CO2 uptake performance (1.74 mmol g−1 at 298 K and 3.19 mmol g−1 at 273 K). Furthermore, this material possesses a high specific capacitance of 453 F g−1 at 5 mV s−1 comparable to others porous carbon materials with excellent columbic efficiencies for 10,000 cycle at 20 A g−1.

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Highly ordered hierarchical porous carbon derived from biomass waste mangosteen peel as superior cathode material for high performance supercapacitor

Cited by 133 publications

References 68 publications

A rod‐like mesoporous carbon derived from agro‐industrial cassava petiole waste for supercapacitor application

A rod‐like mesoporous carbon derived from agro‐industrial cassava petiole waste for supercapacitor application

Nanofiber-enrich activated carbon coin derived from tofu dregs as electrode materials for supercapacitor

Meso/Microporous Carbons from Conjugated Hyper-Crosslinked Polymers Based on Tetraphenylethene for High-Performance CO2 Capture and Supercapacitor

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