Highly selective extraction of aromatics from aliphatics by using metal chloride-based ionic liquids

Yu, Hui; Wu, Xiaojia; Geng, Chuanqi; Li, Xinyu; Du, Chencan; Zhou, Zhiyong; Ren, Zhongqi

doi:10.1016/j.cjche.2023.09.004

Chinese Journal of Chemical Engineering

2024

DOI: 10.1016/j.cjche.2023.09.004

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Highly selective extraction of aromatics from aliphatics by using metal chloride-based ionic liquids

Hui Yu,

Xiaojia Wu,

Chuanqi Geng

et al.

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Cited by 2 publications

References 33 publications

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Simultaneous desulfurization and dearomatization of simulated straight-run diesel with novel green DBN-based ionic liquids

Wu,

Yang,

Wang

et al. 2025

Separation and Purification Technology

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Simultaneous desulfurization and dearomatization of simulated straight-run diesel with novel green DBN-based ionic liquids

Wu,

Yang,

Wang

et al. 2025

Separation and Purification Technology

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Novel ionic liquid systems based on three-nitro phenoxide: Spectroscopic and electronic characterization using theoretical and experimental study

Esfahani,

Akbari,

Soleimani-Amiri

2024

MGC

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After extensive computations, novel trinitro compounds, triethyl ammonium 2,4,6-trinitro phenoxide (TEA-TNP) and tetramethyl guanidinium 2,4,6-trinitro phenoxide (TMG-TNP), are designed, synthesized, and identified. The Geometrical parameters, electronic properties, and spectroscopic analysis have been investigated by comparison of theoretical and experimental methods. Spectrum features that include IR and Raman have been calculated, and 1H and 13C NMR spectra are compared to experimental data. Electronic analysis has been investigated through NLO, FMO, UV-Vis, NBO, and MEP calculations. B3LYP/6-311++G(d,p) is highly successful and dependable for predicting ionic liquid stability, electrical characteristics, and spectroscopy. Both TEA-TNP and TMG-TNP are introduced as suitable candidates for NLO material. TMG-TNP with greater nucleophilicity (N) is a noncorrosive lubricant additive that reduces friction and wear for tribological performance.

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Highly selective extraction of aromatics from aliphatics by using metal chloride-based ionic liquids

Cited by 2 publications

References 33 publications

Simultaneous desulfurization and dearomatization of simulated straight-run diesel with novel green DBN-based ionic liquids

Simultaneous desulfurization and dearomatization of simulated straight-run diesel with novel green DBN-based ionic liquids

Novel ionic liquid systems based on three-nitro phenoxide: Spectroscopic and electronic characterization using theoretical and experimental study

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