Highly selective hydrogenation of dimethyl oxalate to methyl glycolate and ethylene glycol over an amino-assisted Ru-based catalyst

Song, Lei; He, Yan; Zhou, Changan; Shu, Guoqiang; Ma, Kui; Yue, Hairong

doi:10.1039/d2cc03346a

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Emerging Thermal Catalysts For Eg Synthesis1

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Cited by 8 publications

(1 citation statement)

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“…Similarly, the amino decorated MCM-41 was prepared to anchor and stabilize electron-rich Ru active sites for DMO hydrogenation. 60 Besides, a semi-encapsulated Cu@SiO 2 @CNTs catalyst also showed an improved TOF value of 25 h −1 and a boosted stability of over 200 h (Fig. 2b and c).…”

Section: Emerging Thermal Catalysts For Eg Synthesismentioning

confidence: 85%

Emerging catalysts for the ambient synthesis of ethylene glycol from CO₂ and its derivatives

Huang

Chen

et al. 2023

Chem. Commun.

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Section: Emerging Thermal Catalysts For Eg Synthesismentioning

confidence: 85%

Emerging catalysts for the ambient synthesis of ethylene glycol from CO₂ and its derivatives

Huang

Chen

et al. 2023

Chem. Commun.

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Ultrafine Ru Nanoparticles Supported on Mesoporous Silica for Hydrogen Production via Decomposition of Ammonia

Tang,

Ding,

et al. 2024

ChemCatChem

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We reported metallic ruthenium (Ru) nanoparticles loaded on amino modified dendritic mesoporous silica microspheres (Ru/NH2‐DMSMs) for ammonia decomposition to hydrogen. The sizes of the loaded Ru nanoparticles on carrier are 2~3 nm, providing rich active sites for ammonia decomposition reaction. As a result, the obtained Ru/NH2‐DMSMs‐5.1 can afford almost ~100% ammonia decomposition at 550 °C, due to the unique mesoporous structure of DMSMs inhibiting the aggregation of active Ru nanoparticles and enhancing the mass transport of ammonia.

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Optimization and prediction of catalysts for precise synthesis of methyl glycolate from dimethyl oxalate using machine learning coupled with particle swarm optimization algorithm

Yang,

Zhou,

Bao

et al. 2024

Chemical Engineering Science

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Highly selective hydrogenation of dimethyl oxalate to methyl glycolate and ethylene glycol over an amino-assisted Ru-based catalyst

Abstract: A Ru/NH2-MCM-41 catalyst was prepared via a coordination-assisted strategy for chemoselective hydrogenation of dimethyl oxalate with a high selectivity of methyl glycolate (ca. 100%) and ethylene glycol (>90%) at reaction...

Cited by 8 publications

References 25 publications

Emerging catalysts for the ambient synthesis of ethylene glycol from CO₂ and its derivatives

Emerging catalysts for the ambient synthesis of ethylene glycol from CO₂ and its derivatives

Ultrafine Ru Nanoparticles Supported on Mesoporous Silica for Hydrogen Production via Decomposition of Ammonia

Optimization and prediction of catalysts for precise synthesis of methyl glycolate from dimethyl oxalate using machine learning coupled with particle swarm optimization algorithm

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Highly selective hydrogenation of dimethyl oxalate to methyl glycolate and ethylene glycol over an amino-assisted Ru-based catalyst

Abstract: A Ru/NH2-MCM-41 catalyst was prepared via a coordination-assisted strategy for chemoselective hydrogenation of dimethyl oxalate with a high selectivity of methyl glycolate (ca. 100%) and ethylene glycol (>90%) at reaction...

Cited by 8 publications

References 25 publications

Emerging catalysts for the ambient synthesis of ethylene glycol from CO2 and its derivatives

Emerging catalysts for the ambient synthesis of ethylene glycol from CO2 and its derivatives

Ultrafine Ru Nanoparticles Supported on Mesoporous Silica for Hydrogen Production via Decomposition of Ammonia

Optimization and prediction of catalysts for precise synthesis of methyl glycolate from dimethyl oxalate using machine learning coupled with particle swarm optimization algorithm

Contact Info

Product

Resources

About

Emerging catalysts for the ambient synthesis of ethylene glycol from CO₂ and its derivatives

Emerging catalysts for the ambient synthesis of ethylene glycol from CO₂ and its derivatives