Highly selective isomerization of N-allylamides catalyzed by ruthenium and rhodium complexes

Isomerization of alkyl allyl and allyl silyl ethers catalyzed by ruthenium complexes

“…21), the catalyst has been separated on functionalized siliceous foam, as it has been described for some aryl 1-propenyl ethers [12] and enamides [29]. In some cases, successful adsorption of catalyst has been achieved on charcoal.…”

The role of the functional group in double bond migration in allylic systems catalysed by ruthenium hydride complexes

“…enabling Q-allyl isomerisation to Q-(1-propenyl), and also the Q groups (and conditions) enabling transformations other than double bond migration, together with causes of all these effects. We carried out the analysis, basing mainly on the results published earlier [21,[34][35][36][37][38][39][40][41][42][43][44][45][46][47][48][49][50].…”

Phenylphosphoric Acid as a New Additive to Inhibit Olefin Isomerisation in Ruthenium‐Catalysed Metathesis Reactions

“…This species, resulting from isomerisation of 8, has itself three different cis-trans isomers (namely EE, EZ and ZZ) which have been previously characterised by 1 H NMR spectroscopy. [42] On the basis of this, it was possible to assign the resonances corresponding to the olefinic protons of 10 and calculate that the proportion of 8 which isomerised to 10 was ca. 50 % (by 1 H NMR spectroscopy).…”