Highly selective synthesis and near-infrared photothermal conversion of metalla-Borromean ring and [2]catenane assemblies

Abstract

Although the selective synthesis of complicated supramolecular architectures has seen significant progress in recent years, the exploration of the properties of these complexes remains a fascinating challenge. Herein, a series...

Size-Induced Highly Selective Synthesis of Organometallic Rectangular Macrocycles and Heterometallic Cage Based on Half-Sandwich Rhodium Building Block

“…Accompanied by the development of this field, a series of molecular knots [14][15][16][17], catenanes [17][18][19], Borromean rings [20][21][22], Solomon links [23][24][25] and molecular cages [26][27][28] have been designed reasonably and reported continuously. In the process of research, the main synthetic methods were divided into two classes: metal-iontemplated and template free based on coordination-driven methods [29][30][31][32][33]. The former has been utilized to construct various coordination supramolecular compounds.…”

Acridine based metal–organic framework host–guest featuring efficient photoelectrochemical-type photodetector and white LED

“…1–5 Their tunability and structural diversity as well as synthetic convenience enable the application of these materials in a variety of fields, such as materials science, engineering, physics, biomedicine, nanotechnology, and other cognate disciplines. 6–19 During the past decade, a variety of guest-encapsulated MOF systems (Guest@MOFs) and luminescent MOF materials (LMOFs) have also been extensively studied owing to their facile synthesis routes and promising candidates for optoelectronic and photonic applications. 20–30 The LMOFs and Guest@MOFs can be modulated by the richness of metal ions/clusters and organic compounds as linkers.…”

In situgrowth of 2D ZnIn2S4nanosheets on sulfur-doped porous Ti3C2TxMXene 3D multi-functional architectures for photocatalytic H2evolution

“…22–24 Therefore, it is an urgent requirement to design and fabricate noble-metal-free, multifunctional photo-conversion systems. 25…”