Highly selective synthesis of unsymmetrical phthalocyanines from 3,6-Bis(hexadecyloxy)phthalonitrile and their spectral characteristics

Korel’chuk, M. V.; Galanin, N. Е.; Shaposhnikov, G. P.

doi:10.1134/s1070428013040209

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“…The reason is that the two possible isomers, namely ABAB and AABB, are formed and, as the two compounds show similar solubility features, they are frequently eluted in the same fractions. Examples of the preparation of ABAB and AABB Pcs by statistical methods are scarce . Directed approaches have been applied for the selective preparation of each of the isomers .…”

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Efficient Synthesis of ABAB Functionalized Phthalocyanines

et al. 2014

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Efficient Synthesis of ABAB Functionalized Phthalocyanines

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17.9.24 Phthalocyanines and Related Compounds (Update 2017)

Christmann¹,

Paquin²,

Weinreb³

et al. 2017

Knowledge Updates 2017/2

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This review updates the original Science of Synthesis chapter (Section 17.9) on phthalocyanines and various ring-fused, ring-contracted, and ring-expanded analogues. It adds some recently published methods, examples, and variations on the synthesis of unsubstituted phthalocyanines and metal phthalocyanines, as well as identically and nonidentically substituted phthalocyanine derivatives. Besides peripheral substitution, axial functionalization is also discussed, but attention is focused only on those methods that represent appreciable progress for a particular type of metal coordination and axial functionalization, provide phthalocyanines with specific features such as chirality, or allow the functionalization of phthalocyanines with entities that are difficult to introduce at the peripheral sites. This account also includes sections on new types of phthalocyanine derivatives and analogues that were not covered in the original chapter, as well as the progress made in the synthesis of some of these families in the decade since 2003.

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Highly selective synthesis of unsymmetrical phthalocyanines from 3,6-Bis(hexadecyloxy)phthalonitrile and their spectral characteristics

Cited by 2 publications

References 13 publications

Efficient Synthesis of ABAB Functionalized Phthalocyanines

Efficient Synthesis of ABAB Functionalized Phthalocyanines

17.9.24 Phthalocyanines and Related Compounds (Update 2017)

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