Highly Soluble Fluorinated Polyimides Synthesized with Hydrothermal Process towards Sustainable Green Technology

Abstract

Polyimides, a widely used engineering plastic, require use of large amounts of toxic and hazardous organic solvents which threaten our daily lives, calling for new and easy synthetic methods for sustainable environmentally friendly development. In this paper, highly soluble fluorinated polyimides based on 4,4′-(hexafluoroisopropylidene) diphthalic anhydride were synthesized via hydrothermal process without using any toxic organic solvents and the advantages of the newly demonstrated synthetic methods are shown by comparative analysis performed with the two conventional synthetic methods using organic solvent: thermal and chemical imidization. Lower temperature is required (~200 °C) compared to thermal imidization and functional groups for high fusibility formed more easily compared to chemical imidization. According to the comparative analysis, hydrothermally synthesized PIs showed excellent solubility and maintained high thermal stability (>500 °C) and glass transition temperature (>300 °C) compared to conventional PI. The hydrothermally synthesized polyimide is much more convenient to store and manage than other form of polyimide which is much more stable when it is exposed to humidity as it is a powder form. The hydrothermal synthetic method is verified to be a “Green” and facile method for sustainable PI synthesis.

Structural Designs of Transparent Polyimide Films with Low Dielectric Properties and Low Water Absorption: A Review

“…Furthermore, PIs have excellent mechanical properties, including high moduli and tensile strength, which facilitate their use in the wide −270 to +300 °C temperature range [ 31 ]. Even though PIs have suitable properties for high-speed communications, they have some drawbacks, including poor solubility in organic solvents, infusibility, and strong coloration due to charge-transfer-complex (CTC) formation [ 32 , 33 , 34 ].…”