Highly Stereoselective One‐Pot Synthesis of Tetrasubstituted Alkenes via Carbopalladation Reaction of Fluorine‐Containing Acetylene Derivatives.

Abstract

Polyphenylalkene derivatives Q 0740Highly Stereoselective One-Pot Synthesis of Tetrasubstituted Alkenes via Carbopalladation Reaction of Fluorine-Containing Acetylene Derivatives. -The title practical one-pot method is applicable to a variety of fluoroalkylated alkynes, e.g. (I). -(KONNO*, T.; TAKU, K.-I.; ISHIHARA, T.; J. Fluorine Chem. 127 (2006) 7, 966-972; Dep. Chem. Mater. Technol., Kyoto Inst. Technol., Sakyo, Kyoto 606, Japan; Eng.) -Schulze 44-099