In this article, lightweight silver@carbon microsphere@graphene (Ag@CMS@GR) composite materials were fabricated. First, carbon microsphere (CMS) was prepared by redox hydrothermal method in the presence of FeCl 3 and polyvinyl alcohol. Next, on the surface, silver was deposited to form Ag@CMS particles. And finally, the graphene sheets were added to connect Ag@CMS particles to obtain Ag@CMS@GR composites. Because of the silver nanoparticle may form a conductive pathway, Ag@CMS with relative high content of silver nanoparticles show superior EMI shielding properties. Next, graphene was introduced into Ag@CMS with relative low content of silver particles to form Ag@CMS@GR composites, which is helpful for decreasing the apparent density of composites to around 1.01 gÁcm −3 . And the composites also show good EMI shielding properties. The highest SE and specific SE values of Ag@CMS@GR reached 39.26 dB and 38.87 dBÁcm 3 Ág −1 with 5 wt % graphene content. The EMI shielding mechanism of Ag@CMS@GR composites was discussed. It can be potentially used for lightweight EMI shielding applications.Conductive polymers also can be used as matrix for lightweight EMI shielding materials. Polymer metal composites and conductive polymers usually are lightweight, which is always vital factor for the practical EMI shielding application. Compared with other polymer matrix, carbon microspheres (CMSs) have been attracted a great deal of attention in view of relatively low cost, large surface area, excellent corrosion resistance, and low density. It also has extensive application in electrode materials, 18,19 catalyst supports, 20 supercapacitors. At the same time, the preparation of CMSs by hydrothermal method is not complicated. In our laboratory, we have ever prepared a series of PVA CMSs by redox Additional Supporting Information may be found in the online version of this article.