This work deals with designing the optimal shape of the spinning electrode to optimize the distribution of the electric field and suppress the formation of corona discharges on the surface of the electrode during electrospinning using direct current (DC). Some of the solutions used for electrospinning are solved in flammable solvents, such as PVB; therefore, corona discharges are hazardous, as they cause sparks that can cause fires and explosions. The shape optimization was carried out on a plate weir electrode, which uses the principle of free surface spinning. Using the electric field simulation, an analysis of the plate weir spinner was carried out, and its optimization was aimed at minimizing the occurrence of corona discharges, which negatively affect the spinning process. Based on the simulations’ results, the spinning electrode design parameters were adjusted so that an even distribution of the electric field over the entire active surface of the electrode was ensured, and the incidence of corona discharges was prevented. A laboratory experiment was used to validate the function of the design changes in the spinning electrode.