Highly textured Li(Ni0.5Mn0.3Co0.2)O2 thin films on stainless steel as cathode for lithium-ion battery

Clement, Joachim H.; Lynch, T.; Chen, Aiping; Jian, Jie; Wang, Haiyan

doi:10.1016/j.jpowsour.2013.04.140

Cited by 28 publications

(24 citation statements)

References 40 publications

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“…The charge-discharge profiles strongly depended on the film morphology that was tuned by increasing the annealing temperature from 400 to 500 • C. The best electrochemical features were obtained for annealing at 450 • C, showing a discharge plateau of about 3.7 and 3.6 V [111]. Epitaxial and highly textured LiNi 0.5 Mn 0.3 Co 0.2 O 2 (NMC532) thin film cathodes were deposited by a one-step PLD process [112]. Using a laser fluence of Φ = 6 J·cm −2 , T s = 750 • C, and an Li-enriched target (20% Li 2 CO 3 excess), the films were deposited on silicon (111), stainless steel (SS), and c-cut sapphire (0001) substrates.…”

Section: Li(ni Mn Co)o 2 (Nmc)mentioning

confidence: 99%

Pulsed Laser Deposited Films for Microbatteries

Julien

Mauger

2019

Coatings

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This review article presents a survey of the literature on pulsed laser deposited thin film materials used in devices for energy storage and conversion, i.e., lithium microbatteries, supercapacitors, and electrochromic displays. Three classes of materials are considered: Positive electrode materials (cathodes), solid electrolytes, and negative electrode materials (anodes). The growth conditions and electrochemical properties are presented for each material and state-of-the-art of lithium microbatteries are also reported.

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Section: Li(ni Mn Co)o 2 (Nmc)mentioning

confidence: 99%

Pulsed Laser Deposited Films for Microbatteries

Julien

Mauger

2019

Coatings

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“…Jacob et al [117] . deposited LiNi 0.5 Mn 0.3 Co 0.2 O 2 (NMC532) thin films on different substrates in a temperature range between room temperature and 750 °C and laser fluence of 6 J/cm 2 , using a lithium excess of 20 % in the target.…”

Section: Cathode Materialsmentioning

confidence: 99%

Pulsed Laser Deposition as a Tool for the Development of All Solid‐State Microbatteries

Indrizzi

Ohannessian

Pergolesi

et al. 2021

Helvetica Chimica Acta

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All‐solid‐state lithium ion batteries (LIB) are currently the most promising technology for next generation electrochemical energy storage. Many efforts have been devoted in the past years to improve performance and safety of these devices. Nevertheless, issues regarding chemical and mechanical stability of the different components still hinder substantial improvements. Pulsed laser deposition (PLD) has proved to be an outstanding technique for the deposition of thin films of materials of interest for the fabrication of LIB. Thanks to its versatility and possible fine tuning of the thin film properties, PLD promises to be a very powerful tool for the fabrication of model systems which would allow to study in detail material properties and mechanisms contributing to LIB degradation. Nevertheless, PLD presents difficulties in the deposition of LIB components, mainly due to the presence of elements with large difference of atomic mass in their chemical composition. In this review, we report the main challenges and solution strategies used for the deposition through PLD of complex oxides thin films for LIB.

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“…NMC thin films were mainly deposited via PLD and RF sputtering [392][393][394][395][396]. Prathibha et al [394] grew polycrystalline Li(Ni 0.5 Co 0.25 Mn 0.25 )O 2 thin films with mainly (001) and ( 104) orientations on Au-coated Si substrates via RF sputtering, obtaining a good discharge capacity of 57.5 µAh/cm 2 µm.…”

Section: Cathodesmentioning

confidence: 99%

“…The authors demonstrated that the thin film annealed at 700 • C showed the best performance with the highest percentage of (110) oriented grain. Highly (001)-oriented NMC thin films were also synthesized on Au-buffered stainless steel substrates at 750 • C by Jacob et al [393] in which the films showed a discharge capacity of 187 mAh/g. Table 7 summarizes the discharge capacities of different thin-film cathodes.…”

Section: Cathodesmentioning

confidence: 99%

Advances in Materials Design for All-Solid-state Batteries: From Bulk to Thin Films

Yang

Abraham

et al. 2020

Applied Sciences

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All-solid-state batteries (SSBs) are one of the most fascinating next-generation energy storage systems that can provide improved energy density and safety for a wide range of applications from portable electronics to electric vehicles. The development of SSBs was accelerated by the discovery of new materials and the design of nanostructures. In particular, advances in the growth of thin-film battery materials facilitated the development of all solid-state thin-film batteries (SSTFBs)—expanding their applications to microelectronics such as flexible devices and implantable medical devices. However, critical challenges still remain, such as low ionic conductivity of solid electrolytes, interfacial instability and difficulty in controlling thin-film growth. In this review, we discuss the evolution of electrode and electrolyte materials for lithium-based batteries and their adoption in SSBs and SSTFBs. We highlight novel design strategies of bulk and thin-film materials to solve the issues in lithium-based batteries. We also focus on the important advances in thin-film electrodes, electrolytes and interfacial layers with the aim of providing insight into the future design of batteries. Furthermore, various thin-film fabrication techniques are also covered in this review.

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Highly textured Li(Ni0.5Mn0.3Co0.2)O2 thin films on stainless steel as cathode for lithium-ion battery

Cited by 28 publications

References 40 publications

Pulsed Laser Deposited Films for Microbatteries

Pulsed Laser Deposited Films for Microbatteries

Pulsed Laser Deposition as a Tool for the Development of All Solid‐State Microbatteries

Advances in Materials Design for All-Solid-state Batteries: From Bulk to Thin Films

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